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A15843 4-Bromotoluene, 98%

CAS Number
106-38-7
Synonyms
4-Methylbromobenzene

Stock No. Size Price ($) Quantity Availability
A15843-14 25g 21.80
A15843-22 100g 43.20
A15843-36 500g 119.00
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4-Bromotoluene, 98%

MDL
MFCD00000109
EINECS
203-391-8

Chemical Properties

Formula
C7H7Br
Formula Weight
171.04
Melting point
26-29°
Boiling Point
183-184°
Flash Point
85°(185°F)
Density
1.410
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water. Soluble in methanol.

Applications

4-Bromotoluene was used in the synthesis of ketones by Cu/Pd-catalyzed decarboxylative cross-coupling reaction. 4-Bromotoluene undergoes Heck reaction with styrene in the presence of in situ generated palladium complexes of phosphine-functionalized N-heterocyclic carbene ligands.

Notes

Store at room temperature. Keep away from oxidizing agents.

Literature References

Louis-Charles Campeau.; Sophie Rousseaux.; Keith Fagnou. A Solution to the 2-Pyridyl Organometallic Cross-Coupling Problem:? Regioselective Catalytic Direct Arylation of Pyridine N-Oxides. J. Am. Chem. Soc. 2005, 127 (51),18020-18021 .

Janis Louie.; John F. Hartwig. Discrete High Molecular Weight Triarylamine Dendrimers Prepared by Palladium-Catalyzed Amination.J. Am. Chem. Soc. 1997, 119 (48),11695-11696 .

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,1439
Beilstein
1903636
Harmonized Tariff Code
2903.99
TSCA
Yes
RTECS
XS7965600

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