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772-31-6 - Cyclopropyl 4-fluorophenyl ketone, 98% - (4-Fluorobenzoyl)cyclopropane - A15852 - Alfa Aesar

A15852 Cyclopropyl 4-fluorophenyl ketone, 98%

CAS Number
772-31-6
Synonyms
(4-Fluorobenzoyl)cyclopropane

Size Price ($) Quantity Availability
5g 21.76
25g 72.76
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Cyclopropyl 4-fluorophenyl ketone, 98%

MDL
MFCD00013728
EINECS
212-247-3

Chemical Properties

Formula
C10H9FO
Formula Weight
164.18
Boiling Point
119-120°/13mm
Flash Point
100°(212°F)
Density
1.144
Refractive Index
1.5320
Solubility
Not miscible with water.

Applications

It is used in medicine. Indoles undergo smooth alkylation with cyclopropyl ketones in the presence of the CeCl3·7H2O/LiI reagent system in refluxing acetonitrile under neutral conditions to produce the corresponding C-3 substituted indole derivatives in good to high yields and with high selectivity.

Notes

Store at room temperature. Keep away from oxidizing agents.

Literature References

R. Garth Pews.; N. D. Ojha. Electronic properties of three-membered rings. II. Transmission of conjugation by the cyclopropane ring.J. Am. Chem. Soc. 1969, 91 (21),5769-5773 .

Takanori Tanaka.; Yorinobu Yasuda.; Masahiko Hayashi. New Chiral Schiff Base as a Tridentate Ligand for Catalytic Enantioselective Addition of Diethylzinc to Aldehydes J. Org. Chem. 2006, 71 (7091-7093), .

Other References

Beilstein
2044844
Harmonized Tariff Code
2914.70
TSCA
No

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