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A15897 (1S,2R)-(-)-10,2-Camphorsultam, 99%

CAS Number
94594-90-8
Synonyms
(2R)-(-)-Bornane-10,2-sultam

Stock No. Size Price ($) Quantity Availability
A15897-03 1g 67.00
A15897-06 5g 192.00
A15897-14 25g 522.00
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(1S,2R)-(-)-10,2-Camphorsultam, 99%

MDL
MFCD00066271

Chemical Properties

Formula
C10H17NO2S
Formula Weight
215.32
Melting point
181-186°
Storage & Sensitivity
Ambient temperatures.
Solubility
Slightly soluble in water.

Applications

(1S,2R)-(-)-10,2-Camphorsultam is used in the asymmetric synthesis of (S)- and (R)-N-Fmoc-S-trityl-α-methylcysteine. It is used as proton source in the synthesis of chiral α,γ-substituted γ-butyrolactones. It is also employed as a chiral probe for the optical resolution by HPLC and X-ray crystallographic determination of the absolute stereochemistry of carboxylic acids. Also used to prepare N-acryloyl derivatives which are employed as dienophiles in asymmetric Diels-Alder reactions. and for other asymmetric transformations.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong bases and strong oxidizing agents.

Literature References

Satendra Singh.; Samala J Rao.; Michael W Pennington. Efficient asymmetric synthesis of (S)- and (R)-N-Fmoc-S-trityl-alpha-methylcysteine using camphorsultam as a chiral auxiliary. Journal of Organic Chemistry. 2004, 69 (13), 4551-4554.

M H Xu.; W Wang.; L J Xia.; G Q Lin. Gluconobacter cerevisiae sp. nov., isolated from the brewery environment. International Journal of Systematic and Evolutionary Microbiology. 2014, 64 (4), 1134-1141.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
83811
Harmonized Tariff Code
2934.99
TSCA
No

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