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A15924 1-Bromo-4-tert-butylbenzene, 97%

CAS Number
3972-65-4
Synonyms
4-tert-Butylbromobenzene

Stock No. Size Price ($) Quantity Availability
A15924-14 25g 49.20
A15924-22 100g 141.00
A15924-36 500g 522.00
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1-Bromo-4-tert-butylbenzene, 97%

MDL
MFCD00000108
EINECS
223-599-2

Chemical Properties

Formula
C10H13Br
Formula Weight
213.12
Melting point
15-16°
Boiling Point
231-232°
Flash Point
97°(206°F)
Density
1.229
Refractive Index
1.5330
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

1-Bromo-4-tert-butylbenzene was used in the synthesis of 4-tert-butyl-phenylboronic acid1, 1-deoxy analogs of CP-47,497 (n = 0 to 7) and 1-deoxy analogs of CP-55,940 (n = 0 to 7). It undergoes lithium-bromide exchange reactions with n-butyllithium and tert-butyllithium at 0°C in various solvents.

Notes

Store in cool dry place. Keep away from oxidizing agents.

Literature References

Michael Palucki.; Stephen L. Buchwald. Palladium-Catalyzed α-Arylation of Ketones.J. Am. Chem. Soc. 1997, 119 (45),11108-11109 .

Jens Åhman.; John P. Wolfe.; Malisa V. Troutman.; Michael Palucki.; Stephen L. Buchwald. Asymmetric Arylation of Ketone Enolates.J. Am. Chem. Soc. 1998, 120 (8), 1918-1919 .

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1859117
Harmonized Tariff Code
2903.99
TSCA
No

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