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A15942 4-Bromobenzotrifluoride, 99%

CAS Number
402-43-7
Synonyms
4-(Trifluoromethyl)bromobenzene

Stock No. Size Price ($) Quantity Availability
A15942-06 5g 31.50
A15942-14 25g 106.00
A15942-22 100g 334.00
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4-Bromobenzotrifluoride, 99%

MDL
MFCD00000398
EINECS
206-943-6

Chemical Properties

Formula
C7H4BrF3
Formula Weight
225.01
Boiling Point
154-155°
Flash Point
60°(140°F)
Density
1.630
Refractive Index
1.4730
Storage & Sensitivity
Ambient temperatures.
Solubility
Not miscible or difficult to mix.

Applications

4-Bromobenzotrifluoride is used to study the catalytic activity of palladacycle using Suzuki-Miyaura reaction.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which areopened must be carefully resealed and kept upright to prevent leakage. Incompatible with strong bases and strong oxidizing agents.

Literature References

Woen Susanto.; Chi-Yuan Chu.; Wei Jie Ang,.; Tzyy-Chao Chou.; Lee-Chiang Lo.; Yulin Lam. Development of a fluorous, oxime-based palladacycle for microwave-promoted carbon-carbon coupling reactions in aqueous media. Green Chem. 2012, 14 77-80 .

Mark Sundermeier Dr., Alexander Zapf Dr.; Matthias Beller Prof. Dr. A Convenient Procedure for the Palladium-Catalyzed Cyanation of Aryl Halides. Angewandte Chemie International Edition. 2003, 42 (14), 1661-1664.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H315-H319-H335

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
2045666
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2903.99
TSCA
Yes

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