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A16034 2,6-Difluorophenol, 98+%

CAS Number
28177-48-2
Synonyms

Stock No. Size Price ($) Quantity Availability
A16034-06 5g 94.50
A16034-14 25g 316.00
A16034-22 100g 894.00
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2,6-Difluorophenol, 98+%

MDL
MFCD00002158
EINECS
248-884-9

Chemical Properties

Formula
C6H4F2O
Formula Weight
130.09
Melting point
36-40°
Boiling Point
59-61°/17mm
Flash Point
58°(136°F)
Density
1.27
Storage & Sensitivity
Ambient temperatures.
Solubility
Slightly soluble in water. Soluble in ethanol.

Applications

2,6-Difluorophenol undergoes oxidative polymerization in the presence of the Fe-N,N?-bis(salicylidene)ethylenediamine (salen) complex (catalyst) and hydrogen peroxide (oxidizing agent) to give poly(2,6-difluoro-1,4-phenylene oxide). It is also used as pharmaceutical intermediates.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Literature References

Ryohei Ikeda; Hozumi Tanaka; Hiroshi Uyama; Shiro Kobayashi. Oxidative polymerization of 2,6-difluorophenol to crystalline poly(2,6-difluoro-1,4-phenylene oxide). Macromolecules. 2000, 33, (18),6648-6652

 

Jian Qiu; Scott H.Stevenson; Michael J.O'Beirne; Richard B.Silverman . 2,6-Difluorophenol as a bioisostere of a carboxylic acid:? Bioisosteric analogues of γ-aminobutyric acid. J. Med. Chem. 1999, 42, (2),329-332

GHS Hazard and Precautionary Statements

Hazard Statements: H228-H302-H312-H314-H332-H335

Flammable solid. Harmful if swallowed. Harmful in contact with skin. Causes severe skin burns and eye damage. Harmful if inhaled. May cause respiratory irritation.

Precautionary Statements: P210-P240-P241-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
2043613
Hazard Class
4.1
Packing Group
III
Harmonized Tariff Code
2908.19
TSCA
No

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