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A16089 3-Methyl-2-buten-1-ol, 98+%

CAS Number
556-82-1
Synonyms
3,3-Dimethylallyl alcohol
Prenol

Stock No. Size Price ($) Quantity Availability
A16089-14 25g 23.00
A16089-22 100g 64.90
A16089-36 500g 218.00
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3-Methyl-2-buten-1-ol, 98+%

MDL
MFCD00002916
EINECS
209-141-4

Chemical Properties

Formula
C5H10O
Formula Weight
86.13
Boiling Point
139-140°
Flash Point
43°(109°F)
Density
0.860
Refractive Index
1.4440
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water (170 g/L at 20°C).

Applications

3-Methyl-2-buten-1-ol is used as a reagent for protection of carboxylic acids as their 3-methyl-2-buten-1-yl (Prenyl) esters. It is also used in perfumery.

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Literature References

Rodriguez, D.; Rodriguez, A.; Soto, A., Aranda, A.; Diaz-de-Mera, Y.; Notario, A. Kinetics of the reactions of Cl atoms with 2-buten-1-ol, 2-methyl-2-propen-1-ol, and 3-methyl-2-buten-1-ol as a function of temperature. Journal of Atmospheric Chemistry. 2008, 59 (3), 187-197.

Enhong Cao.; Asterios Gavriilidis.; William B. Motherwell. Oxidative dehydrogenation of 3-Methyl-2-buten-1-ol in microreactors. Chemical Engineering Science. 2004, 59 (22-23), 4803-4808.

Reagent for protection of carboxylic acids as their 3-methyl-2-buten-1-yl (Prenyl) esters. Removal can be effected under mild conditions using iodine in cyclohexane: Tetrahedron Lett., 35, 1539 (1994).

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H302-H314-H317

Flammable liquid and vapour. Harmful if swallowed. Causes severe skin burns and eye damage. May cause an allergic skin reaction.

Precautionary Statements: P210-P233-P240-P241-P242-P243-P260-P264b-P270-P272-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P333+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1633479
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2905.29
TSCA
Yes
RTECS
EM9472500

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