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21908-53-2 - Mercury(II) oxide, red, 99% - Mercuric oxide - A16157 - Alfa Aesar

A16157 Mercury(II) oxide, red, 99%

CAS Number
21908-53-2
Synonyms
Mercuric oxide

Size Price ($) Quantity Availability
50g 22.66
250g 92.70
1000g 309.00
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Mercury(II) oxide, red, 99%

MDL
MFCD00011045
EINECS
244-654-7

Chemical Properties

Formula
HgO
Formula Weight
216.59
Melting point
ca 500° dec.
Density
11.14
Solubility
Partially soluble in water. insoluble in alcohol, ether, acetone and ammonia.

Applications

Mercury(II) oxide is used in marine and porcelain paints, dry batteries, chemical reagents, and topical antiseptics. It acts as a significant part in the production of mercury. It is utilitarian in the deduction of a mercury based superconductor. It is likewise employed, as a photo-oxidant for the photochemical oxidation of primary aromatic amines to the corresponding azoaromatic compounds. It is also an essential material for the preparation of cathodes in mercury batteries.

Notes

Light sensitive. Incompatible with hypophosphoric acid, fuels, strong oxidizing agents, strong reducing agents, combustible materials, organic materials and phenols.

Literature References

Wu, S. J.; Katayama, R.; Azhar Uddin, M.; Sasaoka, E.; Xie, Z. M. Study on Reactivity of HgO over Activated Carbon with HCl and SO2 in the Presence of Moisture by Temperature-Programmed Decomposition Desorption Mass Spectrometry. Energy Fuels 2015, 29 (10), 6598-6604.

Smith, R. S.; Wiederhold, J. G.; Kretzschmar, R. Mercury Isotope Fractionation during Precipitation of Metacinnabar ( β-HgS) and Montroydite (HgO). Environ. Sci. Technol. 2015, 49 (7), 4325-4334.

Farhadi, S.; Zaringhadama, P.; Sahamieh, R. Z. Photo-assisted Oxidation of Anilines and Other Primary Aromatic Amines to Azo Compounds Using Mercury(II) Oxide as a Photo-Oxidant. Acta Chim. Slov. 2007, 54, 647-653.

GHS Hazard and Precautionary Statements

Hazard Statements: H300-H310-H330-H373-H400-H410

Fatal if swallowed. Fatal in contact with skin. Fatal if inhaled. May cause damage to organs through prolonged or repeated exposure. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.

Precautionary Statements: P260-P284-P301+P310-P304+P340-P320-P330-P361-P302+P350-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear respiratory protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Specific treatment is urgent (see label). Rinse mouth. Remove/Take off immediately all contaminated clothing. IF ON SKIN: Gently wash with plenty of soap and water. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,5882
Hazard Class
6.1
Packing Group
II
Harmonized Tariff Code
2852.10
TSCA
Yes
RTECS
OW8750000

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