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831-91-4 - Benzyl phenyl sulfide, 98% - A16171 - Alfa Aesar

A16171 Benzyl phenyl sulfide, 98%

CAS Number
831-91-4
Synonyms

Size Price ($) Quantity Availability
25g 44.91
100g 127.72
500g 515.00
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Benzyl phenyl sulfide, 98%

MDL
MFCD00003066
EINECS
212-612-7

Chemical Properties

Formula
C6H5CH2SC6H5
Formula Weight
200.30
Melting point
39-42°
Boiling Point
167-168°/10mm
Flash Point
>110°(230°F)
Solubility
Insoluble in water.

Applications

Benzyl phenyl sulfide is used in dyestuff intermediate, flavor & fragrance intermediate and organic intermediate.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Literature References

Yong Hyeon Yim; Kwan Kim; Myung Soo Kim. Adsorption and decomposition of benzyl phenyl sulfide on silver surface investigated by Raman spectroscopy. J. Phys. Chem. 1990, 94, (6),2552-2556

 

Inhyung Lee; Sang Woo Han; Chang Hwan Kim; Taeg Gyum Kim; Sang Woo Joo; Du-Jeon Jang; Kwan Kim. Surface-induced photoreaction of benzyl phenyl sulfide monolayers on silver and its application to preparing patterned binary monolayers. Langmuir. 2000, 16, (26),9963-9967

Has been used in a sequence for the introduction of an ortho-substituent into aromatic amines by base-induced rearrangement of an amino sulfonium salt: J. Am. Chem. Soc., 100, 7600 (1978):

Lithiation of phenylthioethers, (t-BuLi/HMPA) leads exclusively to the ɑ-lithio derivatives, which react with electrophiles such as alkyl halides and carbonyl compounds: Tetrahedron Lett., 1961 (1977).

Other References

Beilstein
1909409
Harmonized Tariff Code
2930.90
TSCA
No

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