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Glucose was transformed to various furan compounds and carboxylic acids derivatives by heat treatment of autoclave such as levulinic acid, 2-acetylfuran and 2-acetyl-5-methylfuran. using 2-acetyl-5-methylfuran or 1,5-dimethyl-2-pyrrolecarbonitrile as reactants, that the formation of the 4-arylation products. Reaction of 2-acetyl-5-methylfuran 6a with 2-aminoethanol pioduced in 79% yield the aminal.
Keith Basey,; Jack G. Woolley. Alkaloids of Physalis alkekengi. Phytochemistry. 1973, 12 (10), 2557-2559.
Liang Zhang,; Isao Kuniyoshi,; Mitsuyo Hirai,; Makoto Shoda. Oxidation of dimethyl sulfide byPseudomonas acidovorans DMR-11 isolated from peat biofilter. Biotechnology Letters. 1991, 13 (3), 223-228.
Hazard Statements: H227-H301
Combustible liquid. Toxic if swallowed.
Precautionary Statements: P210u-P280a-P301+P310a-P405-P403+P235-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye/face protection. IF SWALLOWED: Immediately call a POISON CENTER/doctor Store locked up. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.