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A16173 1-Iododecane, 98%, stab. with copper

CAS Number
2050-77-3
Synonyms
n-Decyl iodide

Stock No. Size Price ($) Quantity Availability
A16173-14 25g 31.40
A16173-18 50g 57.00
A16173-30 250g 218.00
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1-Iododecane, 98%, stab. with copper

MDL
MFCD00001085
EINECS
218-104-1

Chemical Properties

Formula
C10H21I
Formula Weight
268.18
Melting point
-16°
Boiling Point
264°
Flash Point
96°(204°F)
Density
1.257
Refractive Index
1.4850
Storage & Sensitivity
Light Sensitive. Ambient temperatures.
Solubility
Immiscible with water.

Applications

1-Iododecane is used as a precursor to prepare 9-nonadecanone through palladium-catalyzed carbonylative cross-coupling reaction with 9-octyl-9-borabicyclo[3.3.l]nonane. It is also used as an intermediate in organic synthesis.

Notes

Light sensitive. Incompatible with strong oxidizing agents and strong bases. Keep the container tightly closed.

Literature References

Strawsine, L. M.; Sengupta, A.; Raghavachari, K.; Peters, D. G. Direct Reduction of Alkyl Monohalides at Silver in Dimethylformamide: Effects of Position and Identity of the Halogen. ChemElectroChem 2015, 2 (5), 726-736.

Bilbao, N.; Vázquez-González, V.; Aranda, M. T.; González-Rodríguez, D. Synthesis of 5-/8-Halogenated or Ethynylated Lipophilic Nucleobases as Potential Synthetic Intermediates for Supramolec­ular Chemistry. Eur. J. Org. Chem. 2015, 2015 (32), 7160-7175.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1735228
Harmonized Tariff Code
2903.39
TSCA
Yes
RTECS
HD8705000

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