Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

618-89-3 - Methyl 3-bromobenzoate, 98+% - 3-Bromobenzoic acid methyl ester - A16174 - Alfa Aesar

A16174 Methyl 3-bromobenzoate, 98+%

CAS Number
618-89-3
Synonyms
3-Bromobenzoic acid methyl ester

Size Price ($) Quantity Availability
10g 53.25
50g 174.47
250g 624.00
Add to Cart Add to Quote Request View Item

Methyl 3-bromobenzoate, 98+%

MDL
MFCD00017777
EINECS
210-569-9

Chemical Properties

Formula
C8H7BrO2
Formula Weight
215.05
Melting point
30-33°
Boiling Point
139-140°/35mm
Flash Point
>110°(230°F)
Refractive Index
1.5575
Solubility
Slightly soluble in water.

Applications

Methyl 3-bromobenzoate is used as a reagent in organic synthesis. It is used in the synthesis of tetrahydro dibenzazocine, which acts as an inhibitor of 17beta-hydroxysteroid dehydrogenase type 3. Further, it is used to prepare 3-tert-butylphosphanyl-benzoic acid methyl ester by reacting with tert-butyltrimethylsilylphosphine.

Notes

Incompatible with strong oxidizing agents, strong acids and strong bases.

Literature References

Semmes, J. G.; Bevans, S. L.; Mullins, C. H.; Shaughnessy, K. H. Arylation of diethyl malonate and ethyl cyanoacetate catalyzed by palladium/di-tert-butylneopentylphosphine. Tetrahedron Lett. 2015, 56 (23), 3447-3450.

Peña-López, M.; Rosas-Hernández, A.; Beller, M. Progress on All Ends for Carbon-Carbon Bond Formation through Photoredox Catalysis. Angew. Chem. Int. Ed. 2015, 54 (17), 5006-5008.

Other References

Beilstein
1940810
Harmonized Tariff Code
2916.39
TSCA
Yes

Recommended

  • A12435

    Methyl 2-bromobenzoate, 99%
  • B25423

    Dimethyl acetylsuccinate, 96%
  • A11365

    Ethyl 4-bromobenzoate, 98+%
  • A11826

    Methyl 3-(bromomethyl)benzoate, 97%
  • A14004

    Copper(II) nitrate hemi(pentahydrate), 98%

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware