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A16174 Methyl 3-bromobenzoate, 98+%

CAS Number
618-89-3
Synonyms
3-Bromobenzoic acid methyl ester

Stock No. Size Price ($) Quantity Availability
A16174-09 10g 54.20
A16174-18 50g 196.00
A16174-30 250g 812.00
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Methyl 3-bromobenzoate, 98+%

MDL
MFCD00017777
EINECS
210-569-9

Chemical Properties

Formula
C8H7BrO2
Formula Weight
215.05
Melting point
30-33°
Boiling Point
139-140°/35mm
Flash Point
>110°(230°F)
Refractive Index
1.5575
Storage & Sensitivity
Ambient temperatures.
Solubility
Slightly soluble in water.

Applications

Methyl 3-bromobenzoate is used as a reagent in organic synthesis. It is used in the synthesis of tetrahydro dibenzazocine, which acts as an inhibitor of 17beta-hydroxysteroid dehydrogenase type 3. Further, it is used to prepare 3-tert-butylphosphanyl-benzoic acid methyl ester by reacting with tert-butyltrimethylsilylphosphine.

Notes

Incompatible with strong oxidizing agents, strong acids and strong bases.

Literature References

Semmes, J. G.; Bevans, S. L.; Mullins, C. H.; Shaughnessy, K. H. Arylation of diethyl malonate and ethyl cyanoacetate catalyzed by palladium/di-tert-butylneopentylphosphine. Tetrahedron Lett. 2015, 56 (23), 3447-3450.

Peña-López, M.; Rosas-Hernández, A.; Beller, M. Progress on All Ends for Carbon-Carbon Bond Formation through Photoredox Catalysis. Angew. Chem. Int. Ed. 2015, 54 (17), 5006-5008.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1940810
Harmonized Tariff Code
2916.39
TSCA
Yes

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