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108-05-4 - Vinyl acetate, 99%, stab. with 8-12ppm hydroquinone - Acetic acid vinyl ester - A16247 - Alfa Aesar

A16247 Vinyl acetate, 99%, stab. with 8-12ppm hydroquinone

CAS Number
108-05-4
Synonyms
Acetic acid vinyl ester

Size Price ($) Quantity Availability
100ml 18.64
500ml 22.05
2500ml 47.28
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Vinyl acetate, 99%, stab. with 8-12ppm hydroquinone

MDL
MFCD00008713
EINECS
203-545-4

Chemical Properties

Formula
C4H6O2
Formula Weight
86.09
Melting point
-100°
Boiling Point
72-73°
Flash Point
-8°(18°F)
Density
0.932
Refractive Index
1.3960
Solubility
Slightly miscible with water.

Applications

Vinyl acetate is used in the preparation of polyvinyl acetate emulsions and polyvinyl alcohol. It acts as a precursor to polyvinyl acetate. It serves as an ingredient in furniture-glue. It is also used to prepare copolymers with other monomers such as ethylene, acrylic acid. Further, it is used to make adhesives, paints and plastics.

Notes

Light sensitive. Incompatible with acids, bases, oxidizing agents, peroxides, chlorosulfonic acid, ethylene imine, hydrochloric acid, oleum, nitric acid, sulfuric acid and 2-aminoethanol.

Literature References

For example of mercuric acetate-catalyzed transesterification to long-chain vinyl esters, see: Org. Synth. Coll., 4, 977 (1963).

For thermal [2+2] cycloaddition with chlorotrifluoroethylene, see: Org. Synth. Coll., 5, 235 (1973); and with chlorosulfonyl isocyanate to give a ß-lactam: Org. Synth. Coll., 8, 3 (1993).

Dong, X.; Guan, X.; Jiang, Y.; Ma, J.; Zhang, M. Extension of the TraPPE-UA force field to the simulation of vapor-liquid phase equilibria of vinyl acetate system. J. Mol. Liq. 2015, 209, 520-525.

Belbekhouche, S.; Picton, L.; Le Cerf, D.; Hamaide, T. Pullulan-Based Polymer Surfactants for Vinyl Acetate Miniemulsion Polymerization: Kinetics and Colloidal Stability Investigations. Macromol. Chem. Phys. 2015, 216 (18), 1879-1887.

GHS Hazard and Precautionary Statements

Hazard Statements: H225

Highly flammable liquid and vapour.

Precautionary Statements: P210-P280-P240-P241-P233-P242-P243-P303+P361+P353-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Keep container tightly closed. Use only non-sparking tools. Take precautionary measures against static discharge. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,9992
Beilstein
1209327
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2915.32
TSCA
Yes
RTECS
AK0875000

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