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A16247 Vinyl acetate, 99%, stab. with 8-12ppm hydroquinone

CAS Number
108-05-4
Synonyms
Acetic acid vinyl ester

Stock No. Size Price ($) Quantity Availability
A16247-AE 100ml 19.80
A16247-AP 500ml 26.00
A16247-0F 2500ml 49.80
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Vinyl acetate, 99%, stab. with 8-12ppm hydroquinone

MDL
MFCD00008713
EINECS
203-545-4

Chemical Properties

Formula
C4H6O2
Formula Weight
86.09
Melting point
-100°
Boiling Point
72-73°
Flash Point
-8°(18°F)
Density
0.932
Refractive Index
1.3960
Storage & Sensitivity
Keep Cold.
Solubility
Slightly miscible with water.

Applications

Vinyl acetate is used in the preparation of polyvinyl acetate emulsions and polyvinyl alcohol. It acts as a precursor to polyvinyl acetate. It serves as an ingredient in furniture-glue. It is also used to prepare copolymers with other monomers such as ethylene, acrylic acid. Further, it is used to make adhesives, paints and plastics.

Notes

Light sensitive. Incompatible with acids, bases, oxidizing agents, peroxides, chlorosulfonic acid, ethylene imine, hydrochloric acid, oleum, nitric acid, sulfuric acid and 2-aminoethanol.

Literature References

For example of mercuric acetate-catalyzed transesterification to long-chain vinyl esters, see: Org. Synth. Coll., 4, 977 (1963).

For thermal [2+2] cycloaddition with chlorotrifluoroethylene, see: Org. Synth. Coll., 5, 235 (1973); and with chlorosulfonyl isocyanate to give a ß-lactam: Org. Synth. Coll., 8, 3 (1993).

Dong, X.; Guan, X.; Jiang, Y.; Ma, J.; Zhang, M. Extension of the TraPPE-UA force field to the simulation of vapor-liquid phase equilibria of vinyl acetate system. J. Mol. Liq. 2015, 209, 520-525.

Belbekhouche, S.; Picton, L.; Le Cerf, D.; Hamaide, T. Pullulan-Based Polymer Surfactants for Vinyl Acetate Miniemulsion Polymerization: Kinetics and Colloidal Stability Investigations. Macromol. Chem. Phys. 2015, 216 (18), 1879-1887.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H332-H335-H351

Highly flammable liquid and vapour. Harmful if inhaled. May cause respiratory irritation. Suspected of causing cancer.

Precautionary Statements: P201-P202-P210-P233-P240-P241-P242-P243-P261-P271-P281-P303+P361+P353-P304+P340-P305+P351+P338-P308+P313-P312-P331-P363-P370+P378q-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Call a POISON CENTER or doctor/physician if you feel unwell. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,9992
Beilstein
1209327
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2915.32
TSCA
Yes
RTECS
AK0875000

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