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5892-11-5 - Brucine dihydrate, 98% - A16251 - Alfa Aesar

A16251 Brucine dihydrate, 98%

CAS Number
5892-11-5
Synonyms

Size Price ($) Quantity Availability
10g 34.70
50g 102.00
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Brucine dihydrate, 98%

MDL
MFCD00149384

Chemical Properties

Formula
C23H26N2O4•2H2O
Formula Weight
430.50 (394.47anhy)
Melting point
176-178°
Solubility
Soluble in methanol. Partially soluble Miscible with water.

Applications

Resolving agentBrucine dihydrate is used as a resolving agent for chiral acids.

Notes

Incompatible with strong oxidizing agents, bases and strong reducing agents.

Literature References

Resolving agent for chiral acids.

Białon?ska, A.; Ciunik, Z.; Ilczyszyn, M. M.; Siczek, M. Discrete Cuboidal 15- and 16-Membered Water Clusters in Brucine 3.86-Hydrate, Water Release and Its Consequences. Cryst. Growth Des. 2014, 14 (12), 6537-6541.

Smith, G.; Wermuth, U. D.; Williams, M. L. Resolution of the Chiral (1R,2S) Enantiomer of cis-Cyclohexane-1,2-dicarboxylic Acid in the Brucinium Salt 2,3-Dimethoxy-10-oxostrychnidinium (1R,2S)-2-carboxycyclohexane-1-carboxylate Dihydrate. J. Chem. Crystallogr. 2012, 42 (6), 555-559.

GHS Hazard and Precautionary Statements

Hazard Statements: H300-H330

Fatal if swallowed. Fatal if inhaled.

Precautionary Statements: P260u-P284-P264-P301+P310a-P304+P340-P320-P330-P405-P403+P233-P501a

Wear respiratory protection. Wash thoroughly after handling. IF SWALLOWED: IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Specific treatment is urgent (see label). Rinse mouth. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
6.1
Packing Group
I
Harmonized Tariff Code
2939.80
TSCA
Yes

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