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A16301 (Methoxycarbonylmethyl)triphenylphosphonium bromide, 98+%

CAS Number
1779-58-4
Synonyms
(Carbomethoxymethyl)triphenylphosphonium bromide
Methyl (triphenylphosphonio)acetate bromide

Stock No. Size Price ($) Quantity Availability
A16301-14 25g 29.60
A16301-22 100g 86.00
A16301-36 500g 278.00
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(Methoxycarbonylmethyl)triphenylphosphonium bromide, 98+%

MDL
MFCD00011801
EINECS
217-222-0

Chemical Properties

Formula
CH3O2CCH2P(C6H5)3Br
Formula Weight
415.28
Melting point
ca 163° dec.
Storage & Sensitivity
Hygroscopic. Ambient temperatures.
Solubility
Soluble in methanol(almost transparency).

Applications

(Methoxycarbonylmethyl)triphenylphosphonium bromide is a reactant for the synthesis of GSK-3 inhibitors using the Wittig reaction, substituted furanones for antifungal and cytostatic activities, photochromic dithienylethene derivatives, gem-diiodoalkanes containing allylic alcohols and highly substituted cyclopentenes and brazilanes via Au-catalyzed deoxygenative Nazarov cyclization. As reactant for asymmetric hydrogenation of α,β-unsaturated ester-phosphonates, studies of thermal decomposition of phosphonium alkyl ester salts.

Notes

Hygroscopic. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, water, moisture.

Literature References

Petr Šenel et. al. Antifungal 3,5-disubstituted furanones: From 5-acyloxymethyl to 5-alkylidene derivatives. Bioorganic & Medicinal Chemistry. 2010, 18 (5), 1988-2000.

Oliver Tosic et. al.Photochromic dithienylethenes with extended pi-systems. Photochemical & Photobiological Sciences. 2010, 9,(2), 128-130.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
3812975
Harmonized Tariff Code
2931.39
TSCA
No

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