Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

A16309 Trimethylacetylacetonitrile, 99%

CAS Number
59997-51-2
Synonyms
4,4-Dimethyl-3-oxopentanenitrile
Pivaloylacetonitrile

Stock No. Size Price ($) Quantity Availability
A16309-14 25g 49.80
A16309-22 100g 147.00
A16309-36 500g 534.00
Add to Cart Bulk/Specialty Print Quote View Item

Trimethylacetylacetonitrile, 99%

MDL
MFCD00010208
EINECS
262-017-1

Chemical Properties

Formula
C7H11NO
Formula Weight
125.17
Melting point
66-70°
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

Trimethylacetylacetonitrile is a useful intermediate. 4,4-Dimethyl-3-oxopentanenitrile has been used in the preparation of 4,4-dimethyl-3-oxo-2-benzylpentanenitrile, 4,4-dimethyl-3-oxo-2-(4-hydroxybenzyl)pentanenitrile, 4,4-dimethyl-3-oxo-2-(4-methoxybenzyl)pentanenitrile, 4,4-dimethyl-3-oxo-2-(4-fluorobenzyl)pentanenitrile, 4,4-dimethyl-3-oxo-2-(3,4-methylenedioxybenzyl)pentanenitrile, 1-(5-tert-butyl-2-p-tolyl-2H-pyrazol-3-yl)-3-phenylurea.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, bases.

Literature References

Phillip J Black et. al. Borrowing hydrogen: iridium-catalysed reactions for the formation of C-C bonds from alcohols. . Organic & Biomolecular Chemistry, 2006, 4 1), 116-125 .

John Regan et. al. Pyrazole urea-based inhibitors of p38 MAP kinase: from lead compound to clinical candidate.. Journal name. 2002, 45(14), 2994-3008.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H312-H315-H319-H332-H335

Toxic if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P310-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1746674
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2926.90
TSCA
Yes
RTECS
SA2991000

Recommended

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware