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A16347 (Ethoxycarbonylmethyl)triphenylphosphonium bromide, 98+%

CAS Number
1530-45-6
Synonyms
(Carboethoxymethyl)triphenylphosphonium bromide
Ethyl (triphenylphosphonio)acetate bromide

Stock No. Size Price ($) Quantity Availability
A16347-14 25g 30.80
A16347-22 100g 81.30
A16347-36 500g 363.00
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(Ethoxycarbonylmethyl)triphenylphosphonium bromide, 98+%

MDL
MFCD00011835
EINECS
216-230-1

Chemical Properties

Formula
CH3CH2O2CCH2P(C6H5)3Br
Formula Weight
429.30
Melting point
ca 150° dec.
Storage & Sensitivity
Hygroscopic. Ambient temperatures.
Solubility
It is soluble in water.

Applications

(Ethoxycarbonylmethyl)triphenylphosphonium bromide, is used as a pharmaceutical intermediate.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from Strong oxidizing agents, Strong bases.

Literature References

R Alvarez-Sánchez.; D Basketter.; C Pease. Studies of chemical selectivity of hapten, reactivity, and skin sensitization potency. 3. Synthesis and studies on the reactivity toward model nucleophiles of the 13C. Chem. Res. Toxicol. 2003, 16, (5), 627-636.

A Shaabani.; E Soleimani.; HR Khavasi.; RD Hoffmann. An isocyanide-based three-component reaction: synthesis of fully substituted N-alkyl-2-triphenylphosphoranylidene glutarimides. Tetrahedron Letters. 2006, 47, (31), 5493-5496.

For reaction with trifluoroacetic anhydride and triethylamine, followed by pyrolysis as a route to perfluoroalkyl acetylenes, see: Org. Synth. Coll., 9, 436 (1998):

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
3581273
Harmonized Tariff Code
2931.39
TSCA
No
RTECS
TA2299500

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