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Used in the preparation of regulation of phenolic acid synthesis in Bacillus subtilis. Also used in the bacterial decarboxylation of o-phthalic acids.
Nandi CK,; Hazra MK,; Chakraborty T. Conformational effects on vibronic spectra and excited state dynamics of 3-fluorobenzoic acid dimer. The Journal of Chemical Physics . 2004, 121 (11), 5261-5271.
Lynne H. Thomas,; Gavin A. Craig,; Matthias J. Gutmann,; Andrew Parkin,; Kenneth Shanklande,; Chick C. Wilson. Conformational polymorphism of the molecular complex of 3-fluorobenzoic acid with 4-acetylpyridine. CrystEngComm. 2011, 13 3349-3354.
Lithiation of the unprotected acid, with 2.2 moles of s-BuLi in the presence of TMEDA, occurs at the 2-position; subsequent reaction with hexachloroethane or dibromotetrachloroethane provides access to 2-chloro-3-fluoro- and 2-bromo-3-fluorobenzoic acid respectively: Tetrahedron Lett., 36, 881 (1995); Bull. Soc. Chim. Fr., 133, 133 (1996).
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c
Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant