Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

A16523 Methyl carbamate, 99%

CAS Number
598-55-0
Synonyms
Carbamic acid methyl ester

Stock No. Size Price ($) Quantity Availability
A16523-18 50g 17.80
A16523-22 100g 19.40
A16523-36 500g 48.50
Add to Cart Bulk/Specialty Print Quote View Item

Methyl carbamate, 99%

MDL
MFCD00007964
EINECS
209-939-2

Chemical Properties

Formula
H2NCO2CH3
Formula Weight
75.07
Melting point
54-56°
Boiling Point
176-178°
Flash Point
>100°(212°F)
Density
1.140
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water(20g/L).

Applications

Methyl carbamate was used in the synthesis of protected aminocyclopropanes.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, metals, alkali metals.

Literature References

Qi-Feng Li,; Jun-Wei Wang,; Wen-Sheng Dong,; Mao-Qing Kang,; Xin-Kui Wang,; Shao-Yi Peng. A phosgene-free process for the synthesis of methyl N-phenyl carbamate by the reaction of aniline with methyl carbamate. Journal of Molecular Catalysis A: Chemical. 2004, 212 (1-2), 99-105.

The Na derivative has been used as an ammonia equivalent in the Pd(0)-catalyzed amination of allylic acetates: Chem. Lett., 2123 (1989).

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335-H351

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Suspected of causing cancer.

Precautionary Statements: P201-P202-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P308+P313-P312-P332+P313-P337+P313-P362-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,6036
Beilstein
635779
Harmonized Tariff Code
2924.19
TSCA
Yes
RTECS
FC2450000

Recommended

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware