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Methyl carbamate was used in the synthesis of protected aminocyclopropanes.
Qi-Feng Li,; Jun-Wei Wang,; Wen-Sheng Dong,; Mao-Qing Kang,; Xin-Kui Wang,; Shao-Yi Peng. A phosgene-free process for the synthesis of methyl N-phenyl carbamate by the reaction of aniline with methyl carbamate. Journal of Molecular Catalysis A: Chemical. 2004, 212 (1-2), 99-105.
The Na derivative has been used as an ammonia equivalent in the Pd(0)-catalyzed amination of allylic acetates: Chem. Lett., 2123 (1989).
Hazard Statements: H315-H319-H335-H351
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Suspected of causing cancer.
Precautionary Statements: P201-P202-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P308+P313-P312-P332+P313-P337+P313-P362-P501c
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant