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598-55-0 - Methyl carbamate, 99% - Carbamic acid methyl ester - A16523 - Alfa Aesar

A16523 Methyl carbamate, 99%

CAS Number
598-55-0
Synonyms
Carbamic acid methyl ester

Size Price ($) Quantity Availability
50g 15.57
100g 16.56
500g 46.14
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Methyl carbamate, 99%

MDL
MFCD00007964
EINECS
209-939-2

Chemical Properties

Formula
H2NCO2CH3
Formula Weight
75.07
Melting point
54-56°
Boiling Point
176-178°
Flash Point
>100°(212°F)
Density
1.140
Sensitivity
Moisture Sensitive
Solubility
Soluble in water(20g/L).

Applications

Methyl carbamate was used in the synthesis of protected aminocyclopropanes.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, metals, alkali metals.

Literature References

Qi-Feng Li,; Jun-Wei Wang,; Wen-Sheng Dong,; Mao-Qing Kang,; Xin-Kui Wang,; Shao-Yi Peng. A phosgene-free process for the synthesis of methyl N-phenyl carbamate by the reaction of aniline with methyl carbamate. Journal of Molecular Catalysis A: Chemical. 2004, 212 (1-2), 99-105.

The Na derivative has been used as an ammonia equivalent in the Pd(0)-catalyzed amination of allylic acetates: Chem. Lett., 2123 (1989).

GHS Hazard and Precautionary Statements

Hazard Statements: H351-H315-H319-H335

Suspected of causing cancer. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P201-P261-P280-P281-P305+P351+P338-P304+P340-P362-P312-P405-P501a

Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,6036
Beilstein
635779
Harmonized Tariff Code
2924.19
TSCA
Yes
RTECS
FC2450000

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