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A16545 1-Chloro-3-methyl-2-butene, 95%, stab. with potassium carbonate

CAS Number
503-60-6
Synonyms
3,3-Dimethylallyl chloride
Prenyl chloride

Stock No. Size Price ($) Quantity Availability
A16545-09 10g 57.70
A16545-18 50g 220.00
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1-Chloro-3-methyl-2-butene, 95%, stab. with potassium carbonate

MDL
MFCD00000982
EINECS
207-972-7

Chemical Properties

Formula
C5H9Cl
Formula Weight
104.57
Boiling Point
107-109°
Flash Point
13°(56°F)
Density
0.928
Refractive Index
1.4490
Storage & Sensitivity
Keep Cold.
Solubility
Miscible with chloroform, acetone, diethyl ether and alcohol. Immiscible with water.

Applications

1-Chloro-3-methyl-2-butene is used in the synthesis of geraniol. It is also used as an alkylating agent and as a reagent in hyperforin. Further, it is used as an antibiotic to inhibit growth of tumor cells.

Notes

Incompatible with strong oxidizing agents and strong acids. Store in a cool place.

Literature References

Bernier, U. R.; Kline, D. L.; Allan, S. A.; Barnard, D. R. Laboratory Studies of Aedes aegypti Attraction to Ketones, Sulfides, and Primary Chloroalkanes Tested Alone and in Combination with L-Lactic Acid. J. Am. Mosq. Control Assoc. 2015, 31 (1), 63-70.

Rullah, K.; Aluwi, M. F. F. M.; Yamin, B. M.; Bahari, M. N. A.; Wei, L. S.; Ahmad, S.; Abas, F.; Ismail, N. H.; Jantan, I.; Wai, L. K. Inhibition of prostaglandin E2 production by synthetic minor prenylated chalcones and flavonoids: Synthesis, biological activity, crystal structure, and in silico evaluation. Bioorg. Med. Chem. Lett. 2014, 24 (16), 3826-3834.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H315-H319-H335

Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2903.29
TSCA
Yes
RTECS
EM4298500

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