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585-71-7 - (1-Bromoethyl)benzene, 97% - alpha-Methylbenzyl bromide - 1-Phenylethyl bromide - A16839 - Alfa Aesar

A16839 (1-Bromoethyl)benzene, 97%

CAS Number
585-71-7
Synonyms
alpha-Methylbenzyl bromide
1-Phenylethyl bromide

Size Price ($) Quantity Availability
25g 31.02
100g 88.68
500g 296.00
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(1-Bromoethyl)benzene, 97%

MDL
MFCD00000139
EINECS
209-560-2

Chemical Properties

Formula
C8H9Br
Formula Weight
185.06
Melting point
-65°
Boiling Point
200°
Flash Point
81°(177°F)
Density
1.356
Refractive Index
1.5600
Sensitivity
Moisture Sensitive
Solubility
Soluble in alcohol, ether, and benzene.

Applications

(1-Bromoethyl)benzene has been employed in controlled radical polymerization of styrene, in asymmetric esterification of benzoic acid in the presence of a chiral cyclic guanidine and as initiator in the synthesis of bromine terminated polyp-methoxystyrene and polystyrene via atom transfer radical polymerization.

Notes

Moisture Sensitive. Do not store together with strongly basic and oxidizing materials.

Literature References

F. Seutter-berlage; L. P. C. Delbressine; F. L. M. Smeets & M. A. P. Wagenaars-zegers. Mechanism of formation of mercapturic acids from (1-bromoethyl)benzene and (2-bromoethyl)benzene in the rat. Xenobiotica: the fate of foreign compounds in biological systems.2012, 105 (10), 397-398.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335-H227

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Combustible liquid.

Precautionary Statements: P210-P261-P280-P305+P351+P338-P304+P340-P362-P312-P405-P403+P233-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
507210
Harmonized Tariff Code
2903.99
TSCA
Yes

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