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A16839 (1-Bromoethyl)benzene, 97%

CAS Number
585-71-7
Synonyms
alpha-Methylbenzyl bromide
1-Phenylethyl bromide

Stock No. Size Price ($) Quantity Availability
A16839-14 25g 35.30
A16839-22 100g 91.40
A16839-36 500g 374.00
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(1-Bromoethyl)benzene, 97%

MDL
MFCD00000139
EINECS
209-560-2

Chemical Properties

Formula
C8H9Br
Formula Weight
185.06
Melting point
-65°
Boiling Point
200°
Flash Point
81°(177°F)
Density
1.356
Refractive Index
1.5600
Storage & Sensitivity
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.
Solubility
Soluble in alcohol, ether, and benzene.

Applications

(1-Bromoethyl)benzene has been employed in controlled radical polymerization of styrene, in asymmetric esterification of benzoic acid in the presence of a chiral cyclic guanidine and as initiator in the synthesis of bromine terminated polyp-methoxystyrene and polystyrene via atom transfer radical polymerization.

Notes

Moisture Sensitive. Do not store together with strongly basic and oxidizing materials.

Literature References

F. Seutter-berlage; L. P. C. Delbressine; F. L. M. Smeets & M. A. P. Wagenaars-zegers. Mechanism of formation of mercapturic acids from (1-bromoethyl)benzene and (2-bromoethyl)benzene in the rat. Xenobiotica: the fate of foreign compounds in biological systems.2012, 105 (10), 397-398.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H315-H319-H335

Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P235-P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
507210
Hazard Class
9
Packing Group
III
Harmonized Tariff Code
2903.99
TSCA
Yes

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