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DMSO-d6 is a solvent of choice in NMR spectroscopy, owing to its unique characteristics of dissolving both nonpolar and polar compounds, miscibility with almost all organic solvents and permitting high temperature dynamic NMR studies.
Kang, S. O.; VanderVelde, D.; Powell, D.; Bowman-James, K. Fluoride-facilitated deuterium exchange from DMSO-d6 to polyamide-based cryptands. J. Am. Chem. Soc. 2004, 126(39), 12272-12273.
Cheng, K.; Sorek, H.; Zimmermann, H.; Wemmer, D. E.; Pauly , M. Solution-state 2D NMR spectroscopy of plant cell walls enabled by a dimethylsulfoxide-d6/1-Ethyl-3-methylimidazolium acetate solvent. Anal. Chem. 2013, 85 (6), 3213-3221.
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