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7647-01-0 - Hydrogen chloride, 4M in 1,4-dioxane, 99% - A16935 - Alfa Aesar

A16935 Hydrogen chloride, 4M in 1,4-dioxane, 99%

CAS Number
7647-01-0
Synonyms

Size Price ($) Quantity Availability
0.1mole 28.43
0.5mole 93.32
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Hydrogen chloride, 4M in 1,4-dioxane, 99%

MDL
MFCD00011324
EINECS
231-595-7

Chemical Properties

Formula
ClH
Formula Weight
36.46
Flash Point
17°(63°F)
Density
1.05
Sensitivity
Hygroscopic
Solubility
Miscible with alcohol, ether and 1,4-dioxane.

Applications

Hydrogen chloride, 4M in 1,4-dioxane is used in the preparation of N-methyl-O-benzoylhydroxylamine hydrochloride via reaction with benzoic acid, carbonyldiimidazole and N-methylhydroxylamine hydrochloride.

Notes

Hygroscopic. Air sensitive. Incompatible with strong oxidizing agents, halogens, reducing agents, oxygen, bases and amines.

Literature References

Ito, S.; Takahashi, K.; Nozaki, K. Formal Aryne Polymerization: Use of [2.2. 1] Oxabicyclic Alkenes as Aryne Equivalents. J. Am. Chem. Soc. 2014, 136 (21), 7547-7550..

Kato, E.; Tsuji, H.; Kawabata, J. Selective purification of intestinal maltase complex by affinity chromatography employing an uncompetitive inhibitor as the ligand. Tetrahedron 2015, 71 (9), 1419-1424.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H331-H335-H314-H351

Highly flammable liquid and vapour. Toxic if inhaled. May cause respiratory irritation. Causes severe skin burns and eye damage. Suspected of causing cancer.

Precautionary Statements: P210-P260-P201-P261-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2806.10
TSCA
Yes

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