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124-48-1 - Dibromochloromethane, 98% - Chlorodibromomethane - A16938 - Alfa Aesar

A16938 Dibromochloromethane, 98%

CAS Number
124-48-1
Synonyms
Chlorodibromomethane

Size Price ($) Quantity Availability
5g 23.59
25g 80.34
100g 255.44
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Dibromochloromethane, 98%

MDL
MFCD00000820
EINECS
204-704-0

Chemical Properties

Formula
ClCHBr2
Formula Weight
208.28
Melting point
-22°
Boiling Point
115-118°
Density
2.420
Refractive Index
1.5475
Sensitivity
Moisture & Light Sensitive
Solubility
Not miscible or difficult to mix in water.

Applications

It affords bromochlorocarbene under phase-transfer conditions.

Notes

Moisture & Light Sensitive. Store away from light, water/moisture, oxidizing agents and heat. Store under inert gas.

Literature References

M. Fedoryński.; M. Popławska.; K. Nitschke.; W. Kowalski & M. Mâkosza. A Simple Method for Preparation of Dibromochloromethane and Bromodichloromethane.An International Journal for Rapid Communication of Synthetic Organic Chemistry.,1977,7(4), 287-292.

Y. Yokouchi1.; F. Hasebe.; M. Fujiwara.; H. Takashima.; M. Shiotani.; N. Nishi.; Y. Kanaya.; S. Hashimoto.; P. Fraser.; D. Toom-Sauntry.; H. Mukai.; and Y. Nojiri. Correlations and emission ratios among bromoform, dibromochloromethane, and dibromomethane in the atmosphere.Journal of Geophysical Research: Atmospheres .,2005,110(D23).

Source of bromochlorocarbene in the presence of base and Dibenzo-18-crown-6, A13133. Other conditions give mixtures of carbenes: Synthesis, 783 (1977); Tetrahedron, 33, 363 (1977).

GHS Hazard and Precautionary Statements

Hazard Statements: H341-H302

Suspected of causing genetic defects. Harmful if swallowed.

Precautionary Statements: P201-P281-P264-P270-P202-P301+P312-P308+P313-P330-P405-P501a

Obtain special instructions before use. Use personal protective equipment as required. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Do not handle until all safety precautions have been read and understood. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF exposed or concerned: Get medical advice/attention. Rinse mouth. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,2135
Beilstein
1731046
Harmonized Tariff Code
2903.79
TSCA
Yes
RTECS
PA6360000

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