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A16938 Dibromochloromethane, 97+%

CAS Number
124-48-1
Synonyms
Chlorodibromomethane

Stock No. Size Price ($) Quantity Availability
A16938-06 5g 24.60
A16938-14 25g 82.50
A16938-22 100g 259.00
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Dibromochloromethane, 97+%

MDL
MFCD00000820
EINECS
204-704-0

Chemical Properties

Formula
ClCHBr2
Formula Weight
208.28
Melting point
-22°
Boiling Point
115-118°
Density
2.420
Refractive Index
1.5475
Storage & Sensitivity
Keep Cold. Moisture Sensitive. Light Sensitive. Store under Nitrogen.
Solubility
Not miscible or difficult to mix in water.

Applications

It affords bromochlorocarbene under phase-transfer conditions.

Notes

Moisture & Light Sensitive. Store away from light, water/moisture, oxidizing agents and heat. Store under inert gas.

Literature References

M. Fedoryński.; M. Popławska.; K. Nitschke.; W. Kowalski & M. Mâkosza. A Simple Method for Preparation of Dibromochloromethane and Bromodichloromethane.An International Journal for Rapid Communication of Synthetic Organic Chemistry.,1977,7(4), 287-292.

Y. Yokouchi1.; F. Hasebe.; M. Fujiwara.; H. Takashima.; M. Shiotani.; N. Nishi.; Y. Kanaya.; S. Hashimoto.; P. Fraser.; D. Toom-Sauntry.; H. Mukai.; and Y. Nojiri. Correlations and emission ratios among bromoform, dibromochloromethane, and dibromomethane in the atmosphere.Journal of Geophysical Research: Atmospheres .,2005,110(D23).

Source of bromochlorocarbene in the presence of base and Dibenzo-18-crown-6, A13133. Other conditions give mixtures of carbenes: Synthesis, 783 (1977); Tetrahedron, 33, 363 (1977).

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,2135
Beilstein
1731046
Harmonized Tariff Code
2903.79
TSCA
Yes
RTECS
PA6360000

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