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A17020 1-Bromo-2-iodobenzene, 98+%, stab. with copper

CAS Number
583-55-1
Synonyms
2-Bromoiodobenzene

Stock No. Size Price ($) Quantity Availability
A17020-06 5g 36.70
A17020-14 25g 124.00
A17020-22 100g 375.00
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1-Bromo-2-iodobenzene, 98+%, stab. with copper

MDL
MFCD00001030
EINECS
209-508-9

Chemical Properties

Formula
C6H4BrI
Formula Weight
282.91
Melting point
9-10°
Boiling Point
257°
Flash Point
>110°(230°F)
Density
2.256
Refractive Index
1.6645
Storage & Sensitivity
Light Sensitive. Ambient temperatures.
Solubility
Not miscible or difficult to mix in water.

Applications

2-Bromoiodobenzene is used in the synthesis of diarylamines.

Notes

Light Sensitive. Protect from light. Store away from oxidizing agents.

Literature References

María E Budén.; Victoria A Vaillard.; Sandra E Martin.; Roberto A Rossi. Synthesis of carbazoles by intramolecular arylation of diarylamide anions.J Org Chem.2009,74(12), 4490-4498.

Biao Lu.; Bao Wang.; Yihua Zhang.; and Dawei Ma. CuI-Catalyzed Domino Process to 2,3-Disubstituted Benzofurans from 1-Bromo-2-Iodobenzenes and β-Keto Esters.J. Org. Chem.,2007,72,(14), 5337-5341.

Benzyne precursor. In the presence of excess of a Grignard reagent, the initially formed benzyne undergoes nucleophilic addition to give an ortho-substituted phenylmagnesium halide: Synth. Commun., 18, 1749 (1988).

Regioselective Suzuki coupling with arylboronic acids has been achieved giving 2-bromobiphenyl derivatives: Synlett, 207 (1992).

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1855309
Harmonized Tariff Code
2903.99
TSCA
Yes

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