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2-Bromoiodobenzene is used in the synthesis of diarylamines.
María E Budén.; Victoria A Vaillard.; Sandra E Martin.; Roberto A Rossi. Synthesis of carbazoles by intramolecular arylation of diarylamide anions.J Org Chem.2009,74(12), 4490-4498.
Biao Lu.; Bao Wang.; Yihua Zhang.; and Dawei Ma. CuI-Catalyzed Domino Process to 2,3-Disubstituted Benzofurans from 1-Bromo-2-Iodobenzenes and β-Keto Esters.J. Org. Chem.,2007,72,(14), 5337-5341.
Benzyne precursor. In the presence of excess of a Grignard reagent, the initially formed benzyne undergoes nucleophilic addition to give an ortho-substituted phenylmagnesium halide: Synth. Commun., 18, 1749 (1988).
Regioselective Suzuki coupling with arylboronic acids has been achieved giving 2-bromobiphenyl derivatives: Synlett, 207 (1992).
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c
Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant