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A17176 (S)-(-)-1-(1-Naphthyl)ethylamine, 99%

CAS Number
10420-89-0
Synonyms

Stock No. Size Price ($) Quantity Availability
A17176-03 1g 20.40
A17176-06 5g 83.20
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(S)-(-)-1-(1-Naphthyl)ethylamine, 99%

MDL
MFCD00064179

Chemical Properties

Formula
C12H13N
Formula Weight
171.24
Boiling Point
152-153°/11mm
Flash Point
>110°(230°F)
Density
1.060
Refractive Index
1.6230
Storage & Sensitivity
Air Sensitive. Store under Nitrogen. Keep Cold.
Solubility
Soluble in chloroform, ethanol.

Applications

(S)-(-)-1-(1-Naphthyl)ethylamine, (S)-(-)-1-(1-Naphthyl)ethylamine is used in the asymmetric synthesis of α-cyanocarboxylates. Also used in the synthesis of chiral imadazolin-2-ylidene ligands used in organometallic catalysis. Chiral/Asymmetric synthesis.

Notes

Air Sensitive. Stable under recommended storage conditions. Keep away from acids, acid chlorides, acid anhydrides, oxidizing agents, chloroformates.

Literature References

JM Bonello.; FJ Williams. Aspects of enantioselective heterogeneous catalysis: Structure and reactivity of (S)-(-)-1-(1-naphthyl) ethylamine on Pt {111}. J. Am. Chem. Soc. 2003125 (9),  2723-2729.

NW Alcock.; JM Brown.; DI Hulmes. Synthesis and resolution of 1-(2-diphenylphosphino-1-naphthyl) isoquinoline; a P? N chelating ligand for asymmetric catalysis. Tetrahedron: Asymmetry. 19934 (4), 743-756.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H314-H335

Toxic if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
2208024
Harmonized Tariff Code
2921.49
TSCA
Yes

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