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6968-24-7 - 2,6-Dibromo-4-methylaniline, 98+% - 2,6-Dibromo-p-toluidine - A17184 - Alfa Aesar

A17184 2,6-Dibromo-4-methylaniline, 98+%

CAS Number
6968-24-7
Synonyms
2,6-Dibromo-p-toluidine

Size Price ($) Quantity Availability
25g 54.38
100g 150.44
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2,6-Dibromo-4-methylaniline, 98+%

MDL
MFCD00007641
EINECS
230-182-9

Chemical Properties

Formula
C7H7Br2N
Formula Weight
264.96
Melting point
72-76°
Solubility
Insoluble in water.

Applications

2,6-Dibromo-4-methylaniline is used as coupling reagent in spectrophotometric determination of carbaryl in various environmental samples. It was also in preparation of 2-bromo-6-iodo-4-methylaniline. 2,6-Dibromo-4-methylaniline undergoes Suzuki-coupling reaction with 2-dihydroxyboryl-3-methyl-2-cyclopenten-1-one during synthesis of the dinuclear dichlorotitanium complexes. 2,6-Dibromo-4-methylaniline is also used as an intermediate for the synthesis of pharmaceutucals, agrochemicals, dyes and other organic chemicals.

Notes

Stable under ordinary conditions.

Literature References

RR Holmes.; RP Bayer. A Simple Method for the Direct Oxidation of Aromatic Amines to Nitroso Compounds1. J. Am. Chem. Soc. 196082 (13), 3454-3456.

HK Lee.; TM Rana. Microwave-assisted parallel synthesis of a 4, 6-diamino-2, 2-dimethyl-1, 2-dihydro-1-phenyl-s-triazine library. J. Comb. Chem.20046 (4), 504-508.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H311-H332-H315-H319-H335

Toxic if swallowed. Toxic in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P301+P310-P305+P351+P338-P361-P304+P340-P362-P312-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Remove/Take off immediately all contaminated clothing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2085782
Harmonized Tariff Code
2921.43
TSCA
No

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