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A17184 2,6-Dibromo-4-methylaniline, 98+%

CAS Number
6968-24-7
Synonyms
2,6-Dibromo-p-toluidine

Stock No. Size Price ($) Quantity Availability
A17184-14 25g 50.20
A17184-22 100g 147.00
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2,6-Dibromo-4-methylaniline, 98+%

MDL
MFCD00007641
EINECS
230-182-9

Chemical Properties

Formula
C7H7Br2N
Formula Weight
264.96
Melting point
72-76°
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

2,6-Dibromo-4-methylaniline is used as coupling reagent in spectrophotometric determination of carbaryl in various environmental samples. It was also in preparation of 2-bromo-6-iodo-4-methylaniline. 2,6-Dibromo-4-methylaniline undergoes Suzuki-coupling reaction with 2-dihydroxyboryl-3-methyl-2-cyclopenten-1-one during synthesis of the dinuclear dichlorotitanium complexes. 2,6-Dibromo-4-methylaniline is also used as an intermediate for the synthesis of pharmaceutucals, agrochemicals, dyes and other organic chemicals.

Notes

Stable under ordinary conditions.

Literature References

RR Holmes.; RP Bayer. A Simple Method for the Direct Oxidation of Aromatic Amines to Nitroso Compounds1. J. Am. Chem. Soc. 196082 (13), 3454-3456.

HK Lee.; TM Rana. Microwave-assisted parallel synthesis of a 4, 6-diamino-2, 2-dimethyl-1, 2-dihydro-1-phenyl-s-triazine library. J. Comb. Chem.20046 (4), 504-508.

GHS Hazard and Precautionary Statements

Hazard Statements: H302+H312+H332-H315-H319-H335

Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
2085782
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2921.43
TSCA
No

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