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A17250 Dimethyl pyridine-2,5-dicarboxylate, 98+%

CAS Number
881-86-7
Synonyms
Dimethyl isocinchomeronate
Pyridine-2,5-dicarboxylic acid dimethyl ester

Stock No. Size Price ($) Quantity Availability
A17250-03 1g 22.70
A17250-06 5g 28.50
A17250-14 25g 90.70
A17250-22 100g 355.00
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Dimethyl pyridine-2,5-dicarboxylate, 98+%

MDL
MFCD00034767

Chemical Properties

Formula
C9H9NO4
Formula Weight
195.17
Melting point
160-163°
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in Dichloromethane and Ethyl Acetate. Insoluble in water.

Applications

It is the intermediate in the synthesis of potent antitumor agents.

Notes

Store at -20°C. Incompatible with oxidizing agents, reducing agents, bases.

Literature References

Zhenrong Guo.; Eric D Dowdy.; Wen-Sen Li.; Richard Polniaszek.; Edward Delaney. A novel method for the mild and selective amidation of diesters and the amidation of monoesters. Tetrahedron Lett. 2001, 42 (10),1843-1845.

Richard D. Webster.; Alan M. Bond.; Richard G. Compton. Voltammetric and EPR Spectroscopic Studies Associated with the Reduction of Pyridine- and Benzene-Substituted n-Alkyl Esters and Thioic S-Esters in Aprotic Solvents. J. Phys. Chem. 1996, 100 (24),10288-10297.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
172251
Harmonized Tariff Code
2933.39
TSCA
No

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