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85118-00-9 - 2,6-Difluorobenzyl bromide, 97+% - alpha-Bromo-2,6-difluorotoluene - A17434 - Alfa Aesar

A17434 2,6-Difluorobenzyl bromide, 97+%

CAS Number
85118-00-9
Synonyms
alpha-Bromo-2,6-difluorotoluene

Size Price ($) Quantity Availability
5g 51.91
25g 156.03
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2,6-Difluorobenzyl bromide, 97+%

MDL
MFCD00000329
EINECS
285-652-6

Chemical Properties

Formula
C7H5BrF2
Formula Weight
207.02
Melting point
49-53°
Flash Point
>110°(230°F)
Density
1.600

Literature References

Reagent for protection of alcohols as 2,6-difluorobenzyl ethers which can be formed in the presence of Ba(OH)2 in DMF: Helv. Chim. Acta, 79, 1159 (1996). Unlike benzyl ethers, these are stable during cationic reactions. They can be cleaved by dissolving metal reduction (Ca/NH3): Chimia, 329 (1991).

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GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2083943
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2903.99
TSCA
No

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