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Ethyltriphenylphosphonium iodide is involved in synthesis of diarylmethine derivatives, phosphonium salts, and bismuth(III) polynuclear halide complexes, asymmetric hydrogenation.
Carl Michael Dicken.; Philip DeShong. Reactions at high pressures. [3+2] Dipolar cycloaddition of nitrones with vinyl ethers. J. Org. Chem. 1982, 47, (11), 2047-2051.
Andrzej Robert Daniewski.; Jaroslaw Kiegiel. A simple way to (3aR,4S,7aS)-(Z)-ethylideneoctahydro-7a-methyl-1H-4-indenol, a synthon for total synthesis of vitamins D. J. Org. Chem. 1988, 53, (23), 5534-5535.
The phosphorane, generated by reaction with n-BuLi, reacts with nitriles to give high yields of ketones: J. Am. Chem. Soc., 89, 7009 (1967).
Hazard Statements: H301-H312-H315-H319
Toxic if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation.
Precautionary Statements: P264b-P270-P280-P301+P310-P302+P352-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P501c
Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant