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A17576 Cyclohexanol, 99%

CAS Number
108-93-0
Synonyms

Stock No. Size Price ($) Quantity Availability
A17576-AE 100ml 18.20
A17576-AP 500ml 29.20
A17576-0F 2500ml 85.70
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Cyclohexanol, 99%

MDL
MFCD00003855
EINECS
203-630-6

Chemical Properties

Formula
C6H12O
Formula Weight
100.16
Melting point
23-24°
Boiling Point
160-161°
Flash Point
67°(152°F)
Density
0.951
Refractive Index
1.4650
Storage & Sensitivity
Ambient temperatures.
Solubility
Miscible with ethanol, ethyl ether acetone, chloroform, ethyl acetate, linseed oil and benzene. Slightly miscible with cold water.

Applications

Cyclohexanol is used in making soaps, dry cleaning agents and plasticizers. It acts as a solvent for rubber, resins, nitrocellulose, metallic soaps, oils, esters and ethers. It is used in the preparation of adipic acid, hexamethylene diamine, cyclohexanone and caprolactam. It acts as a soap stabilizing agent, disinfection medicated soap and detergent emulsion. It is also useful for paint blending agent, leather degreasing agent and polishes.

Notes

Hygroscopic. Incompatible with strong oxidizing agents, hydrogen peroxide and nitric acid.

Literature References

Cyclohexyl esters can be used to protect carboxylic acids, including aspartate residues in peptide synthesis, resulting in reduced aspartimide formation during acidic or basic reactions: Synthesis, 361 (1992). They are relatively stable to TFA but can be readily cleaved by TfOH or HF: Int. J. Pept. Protein Res., 13, 418 (1979); Tetrahedron Lett., 4033 (1979); Chem. Pharm. Bull., 34, 864 (1986). See also 2,4-Dimethyl-3-pentanol, B20821 .

Schemeth, D.; Noël, J. C.; Jakschitz, T.; Rainer, M.; Tessadri, R.; Huck, C. W.; Bonn, G. K. Poly(N-vinylimidazole/ethylene glycol dimethacrylate) for the purification and isolation of phenolic acids. Anal. Chim. Acta 2015, 885, 199-206.

Zhang, P.; Deng, J.; Mao, J.; Li, H.; Wang, Y. Selective aerobic oxidation of alcohols by a mesoporous graphitic carbon nitride/N-hydroxyphthalimide system under visible-light illumination at room temperature. Chin. J. Catal. 2015, 36 (9), 1580-1586.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H302-H315-H319-H332-H335

Combustible liquid. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation.

Precautionary Statements: P210-P235-P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,2725
Beilstein
906744
Harmonized Tariff Code
2906.12
TSCA
Yes
RTECS
GV7875000

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