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108-93-0 - Cyclohexanol, 99% - A17576 - Alfa Aesar

A17576 Cyclohexanol, 99%

CAS Number
108-93-0
Synonyms

Size Price ($) Quantity Availability
100ml 16.73
500ml 24.39
2500ml 80.86
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Cyclohexanol, 99%

MDL
MFCD00003855
EINECS
203-630-6

Chemical Properties

Formula
C6H12O
Formula Weight
100.16
Melting point
23-24°
Boiling Point
160-161°
Flash Point
67°(152°F)
Density
0.951
Refractive Index
1.4650
Solubility
Miscible with ethanol, ethyl ether acetone, chloroform, ethyl acetate, linseed oil and benzene. Slightly miscible with cold water.

Applications

Cyclohexanol is used in making soaps, dry cleaning agents and plasticizers. It acts as a solvent for rubber, resins, nitrocellulose, metallic soaps, oils, esters and ethers. It is used in the preparation of adipic acid, hexamethylene diamine, cyclohexanone and caprolactam. It acts as a soap stabilizing agent, disinfection medicated soap and detergent emulsion. It is also useful for paint blending agent, leather degreasing agent and polishes.

Notes

Hygroscopic. Incompatible with strong oxidizing agents, hydrogen peroxide and nitric acid.

Literature References

Cyclohexyl esters can be used to protect carboxylic acids, including aspartate residues in peptide synthesis, resulting in reduced aspartimide formation during acidic or basic reactions: Synthesis, 361 (1992). They are relatively stable to TFA but can be readily cleaved by TfOH or HF: Int. J. Pept. Protein Res., 13, 418 (1979); Tetrahedron Lett., 4033 (1979); Chem. Pharm. Bull., 34, 864 (1986). See also 2,4-Dimethyl-3-pentanol, B20821 .

Schemeth, D.; Noël, J. C.; Jakschitz, T.; Rainer, M.; Tessadri, R.; Huck, C. W.; Bonn, G. K. Poly(N-vinylimidazole/ethylene glycol dimethacrylate) for the purification and isolation of phenolic acids. Anal. Chim. Acta 2015, 885, 199-206.

Zhang, P.; Deng, J.; Mao, J.; Li, H.; Wang, Y. Selective aerobic oxidation of alcohols by a mesoporous graphitic carbon nitride/N-hydroxyphthalimide system under visible-light illumination at room temperature. Chin. J. Catal. 2015, 36 (9), 1580-1586.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H332-H315-H335-H227

Harmful if swallowed. Harmful if inhaled. Causes skin irritation. May cause respiratory irritation. Combustible liquid.

Precautionary Statements: P210-P261-P280-P304+P340-P362-P301+P312-P312-P405-P403+P233-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,2725
Beilstein
906744
Harmonized Tariff Code
2906.12
TSCA
Yes
RTECS
GV7875000

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