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A17600 4-Fluorothiophenol, 98+% (dry wt.), water <7%

CAS Number
371-42-6
Synonyms
4-Fluorobenzenethiol

Stock No. Size Price ($) Quantity Availability
A17600-06 5g 46.80
A17600-14 25g 122.00
A17600-22 100g 329.00
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4-Fluorothiophenol, 98+% (dry wt.), water <7%

MDL
MFCD00004846
EINECS
206-737-6

Chemical Properties

Formula
C6H5FS
Formula Weight
128.17
Boiling Point
170-172°
Flash Point
57°(135°F)
Density
1.203
Refractive Index
1.5500
Storage & Sensitivity
Air Sensitive. Ambient temperatures.
Solubility
Not miscible or difficult to mix in water.

Applications

It is used in the synthesis of Bicalutamide, an anti-cancer drug.

Notes

Air Sensitive. Keep away from oxidizing agents and air. Store under inert gas.

Literature References

Bang-Chi Chen.; Rulin Zhao.; Stacey Gove.; Bei Wang.; Joseph E. Sundeen.; Mark E. Salvati.; and Joel C. Barrish. Nucleophilic Aromatic Substitution of Methacrylamide Anion and Its Application to the Synthesis of the Anticancer Drug Bicalutamide.J. Org. Chem.,2003,68(26), 10181-10182.

Wenting Dong.; Wendell Rhine.; Greg Caggiano.; Owen R. Evans.; George Gould.; John White.; Jeff Sharp.; Pat Gilbert.; Shreyashi Ganguly and Stephanie L. Brock. Characterization of bismuth telluride aerogels for thermoelectric applications.Cambridge Journals Online; MRS Proceedings, 2011,1036.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H301-H311-H315-H319-H331-H335

Flammable liquid and vapour. Toxic if swallowed. Toxic in contact with skin. Causes skin irritation. Causes serious eye irritation. Toxic if inhaled. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P261-P264b-P270-P271-P280-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P311-P312-P330-P332+P313-P337+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1446350
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2930.90
TSCA
No

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