Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

838-57-3 - Ethyl 4-nitrobenzoylacetate, 97% - 4-Nitrobenzoylacetic acid ethyl ester - A17603 - Alfa Aesar

A17603 Ethyl 4-nitrobenzoylacetate, 97%

CAS Number
838-57-3
Synonyms
4-Nitrobenzoylacetic acid ethyl ester

Size Price ($) Quantity Availability
10g 56.80
50g 248.00
250g 1031.00
Add to Cart Add to Quote Request View Item

Ethyl 4-nitrobenzoylacetate, 97%

MDL
MFCD00007357
EINECS
212-656-7

Chemical Properties

Formula
C11H11NO5
Formula Weight
237.21
Melting point
68-73°

Applications

It is employed as a reactant involved in synthesis of β-1,3-dicarbonyl aldehydes via oxidation, knoevenagel condensation using a lysine catalyst, and cycloisomerization for the synthesis of trisubstituted furans. It is also a reactant for the fluorination by HF and iodosylbenzene, intramolecular Michael addition reactions and synthesis of diols. Also applied in the synthesis of diols via reduction of aromatic and aliphatic ketos esters6 and cross-coupling reactions for stereo selective synthesis of unsymmetrical 1,4-enediones.

Notes

Store away from oxidizing agents. Keep the container tightly closed in a cool, dry place.

Literature References

Weiping Liu.; Jinhua Liu.; Daisuke Ogawa.; Yasushi Nishihara.; Xingwei Guo.; Zhiping Li. Iron-catalyzed oxidation of tertiary amines: synthesis of β-1,3-dicarbonyl aldehydes by three-component C-C couplings.Org Lett.,2011,13(23), 6272-6275.

Tsugio Kitamura.; Satoshi Kuriki.; Mohammad Hasan Morshed.; Yuji Hori. A practical and convenient fluorination of 1,3-dicarbonyl compounds using aqueous HF in the presence of iodosylbenzene.Org Lett.2011,13(9), 2392-2394.

Other References

Beilstein
1124763
Harmonized Tariff Code
2918.30
TSCA
Yes
RTECS
AJ1073500

Recommended

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware