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A17632 2,2'-Dibromobiphenyl, 98%

CAS Number
13029-09-9
Synonyms

Stock No. Size Price ($) Quantity Availability
A17632-03 1g 54.00
A17632-06 5g 178.00
A17632-14 25g 677.00
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2,2'-Dibromobiphenyl, 98%

MDL
MFCD00093707

Chemical Properties

Formula
C12H8Br2
Formula Weight
312.02
Melting point
78-81°
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

2,2'-Dibromobiphenyl is used to produce 5,5-dimethyl-5H-dibenzosilole at the temperature of -78 - 20°C. It will need reagent n-BuLi and solvents diethyl ether, hexane.

Notes

Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literature References

Herny Gilman, Bernard Gaj. Notes - Coupling Reactions with Some Organolithium Compounds in Tetrahydrofuran. J. Org. Chem. 1957, 22, (4), 447-449.

M.D. Rausch.; G.A. Moser.; C.F. Meade. The isolation, characterization and synthetic utility of several solid organolithium compounds. Journal of Organometallic Chemistry. 1973, 51, 1-11.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
9
Packing Group
II
Harmonized Tariff Code
2903.99
TSCA
No

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