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93-04-9 - 2-Methoxynaphthalene, 98% - Methyl 2-naphthyl ether - A17650 - Alfa Aesar

A17650 2-Methoxynaphthalene, 98%

CAS Number
93-04-9
Synonyms
Methyl 2-naphthyl ether

Size Price ($) Quantity Availability
250g 32.96
1000g 99.19
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2-Methoxynaphthalene, 98%

MDL
MFCD00004061
EINECS
202-213-6

Chemical Properties

Formula
C11H10O
Formula Weight
158.20
Melting point
70-75°
Boiling Point
272-274°
Flash Point
ca 139°(282°F)
Solubility
Soluble in benzene, carbon disulfide, diethyl ether. Insoluble in water.

Applications

2-methoxynaphthalene acylation is used as a model reaction to study the catalytic benefits of delamination. It was also used to study the alkali-metal-mediated manganation (AMMMn) reactions.

Notes

Keep container tightly closed. Store away from oxidizing agents.

Literature References

Eric A. Gunnewegh.; Saritha S. Gopie.; Herman van Bekkum. MCM-41 type molecular sieves as catalysts for the Friedel-Crafts acylation of 2-methoxynaphthalene. Journal of Molecular Catalysis A: Chemical. 1996, 106, (1-2), 151-158.

P. Andy.; J. Garcia-Martinez.; G. Lee.; H. Gonzalez.; C.W. Jones.; M.E. Davis. Acylation of 2-Methoxynaphthalene and Isobutylbenzene over Zeolite Beta. Journal of Catalysis. 2000, 192, (1), 215-223.

The 3-lithio-derivative (n-BuLi) has been reacted with electrophiles, e.g. allyl bromide, ethylene oxide, etc.: Chem. Ind. (London), 1529 (1963); Indian J. Chem., 7, 536 (1969).

For Friedel-Crafts acylation at the 6-position, see: Org. Synth. Coll., 6, 34 (1988). For conditions for minimizing the competing 1-acylation, see: Synth. Commun., 20, 383 (1990).

Other References

Merck
14,5997
Beilstein
1859408
Harmonized Tariff Code
2909.30
TSCA
Yes
RTECS
QJ9468750

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