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41175-50-2 - 8-Hydroxyjulolidine, 97% - 2,3,6,7-Tetrahydro-1H,5H-benzo[ij]quinolizin-8-ol - A17692 - Alfa Aesar

A17692 8-Hydroxyjulolidine, 97%

CAS Number
41175-50-2
Synonyms
2,3,6,7-Tetrahydro-1H,5H-benzo[ij]quinolizin-8-ol

Size Price ($) Quantity Availability
1g 56.10
5g 178.00
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8-Hydroxyjulolidine, 97%

MDL
MFCD00006918
EINECS
255-247-9

Chemical Properties

Formula
C12H15NO
Formula Weight
189.26
Melting point
132-135°
Solubility
Soluble in water (partly), ethanol, chloroform, methanol, and acetone.

Applications

8-Hydroxyjulolidine is used as an intermediate in the preparation of aminocoumarins via microwave-accelerated Pechmann reaction. It is also employed as a starting material for coumarin C-ribosides.

Notes

Store away from oxidizing agents and strong bases. Keep the container tightly closed in a cool, dry place.

Literature References

Scott A. Hilderbrand.; Ralph Weissleder. One-pot synthesis of new symmetric and asymmetric xanthene dyes.Tetrahedron Lett.2007,48(25),4383-4385.

Jin Young Noh.; Soojin Kim.; In Hong Hwang.; Ga Ye Lee.; Juhye Kang.; So Hyun Kim.; Jisook Min.; Sungsu Park.; Cheal Kim.; Jinheung Kim. Solvent-dependent selective fluorescence assay of aluminum and gallium ions using julolidine-based probe.Dyes and Pigments,.2013,99(3), 1016-1021.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Beilstein
1530423
Harmonized Tariff Code
2933.99
TSCA
Yes

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