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A17692 8-Hydroxyjulolidine, 97%

CAS Number
41175-50-2
Synonyms
2,3,6,7-Tetrahydro-1H,5H-benzo[ij]quinolizin-8-ol

Stock No. Size Price ($) Quantity Availability
A17692-03 1g 55.50
A17692-06 5g 181.00
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8-Hydroxyjulolidine, 97%

MDL
MFCD00006918
EINECS
255-247-9

Chemical Properties

Formula
C12H15NO
Formula Weight
189.26
Melting point
132-135°
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water (partly), ethanol, chloroform, methanol, and acetone.

Applications

8-Hydroxyjulolidine is used as an intermediate in the preparation of aminocoumarins via microwave-accelerated Pechmann reaction. It is also employed as a starting material for coumarin C-ribosides.

Notes

Store away from oxidizing agents and strong bases. Keep the container tightly closed in a cool, dry place.

Literature References

Scott A. Hilderbrand.; Ralph Weissleder. One-pot synthesis of new symmetric and asymmetric xanthene dyes.Tetrahedron Lett.2007,48(25),4383-4385.

Jin Young Noh.; Soojin Kim.; In Hong Hwang.; Ga Ye Lee.; Juhye Kang.; So Hyun Kim.; Jisook Min.; Sungsu Park.; Cheal Kim.; Jinheung Kim. Solvent-dependent selective fluorescence assay of aluminum and gallium ions using julolidine-based probe.Dyes and Pigments,.2013,99(3), 1016-1021.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1530423
Harmonized Tariff Code
2933.99
TSCA
Yes

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