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A17705 1-Bromo-4-nitrobenzene, 98%

CAS Number
586-78-7
Synonyms
4-Bromonitrobenzene

Stock No. Size Price ($) Quantity Availability
A17705-06 5g 23.40
A17705-14 25g 61.50
A17705-22 100g 186.00
A17705-36 500g 795.00
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1-Bromo-4-nitrobenzene, 98%

MDL
MFCD00007280
EINECS
209-583-8

Chemical Properties

Formula
C6H4BrNO2
Formula Weight
202.01
Melting point
124-127°
Boiling Point
254-256°
Density
1.948
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water. Almost transparent in hot ethyl alcohol. Soluble in ether

Applications

It can be employed as a syntheses material intermediate. It is also used as a pharmaceutical intermediate.

Notes

Store away from oxidizing agents and bases. Keep the container tightly closed in a cool, dry place.

Literature References

Sven Ernst.; Sarah E Norman.; Christopher Hardacre.; Richard G Compton. The electrochemical reduction of 1-bromo-4-nitrobenzene at zinc electrodes in a room-temperature ionic liquid: a facile route for the formation of arylzinc compounds.Phys Chem Chem Phys.2014,16(10), 4478-4482.

Jin-Heng Li.; Yun Liang.; De-Ping Wang.; Wen-Jie Liu.; Ye-Xiang Xie.; Du-Lin Yin. Efficient Stille cross-coupling reaction catalyzed by the Pd(OAc)2/Dabco catalytic system.J Org Chem.2005,70(7), 2832-2834.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H312-H315-H319-H332-H335-H373

Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P260-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P314-P330-P332+P313-P337+P313-P362-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention if you feel unwell. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
636964
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2904.99
TSCA
Yes
RTECS
CY9040550

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