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586-78-7 - 1-Bromo-4-nitrobenzene, 98% - 4-Bromonitrobenzene - A17705 - Alfa Aesar

A17705 1-Bromo-4-nitrobenzene, 98%

CAS Number
586-78-7
Synonyms
4-Bromonitrobenzene

Size Price ($) Quantity Availability
5g 21.06
25g 59.64
100g 151.20
500g 599.20
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1-Bromo-4-nitrobenzene, 98%

MDL
MFCD00007280
EINECS
209-583-8

Chemical Properties

Formula
C6H4BrNO2
Formula Weight
202.01
Melting point
124-127°
Boiling Point
254-256°
Density
1.948
Solubility
Insoluble in water. Almost transparent in hot ethyl alcohol. Soluble in ether

Applications

It can be employed as a syntheses material intermediate. It is also used as a pharmaceutical intermediate.

Notes

Store away from oxidizing agents and bases. Keep the container tightly closed in a cool, dry place.

Literature References

Sven Ernst.; Sarah E Norman.; Christopher Hardacre.; Richard G Compton. The electrochemical reduction of 1-bromo-4-nitrobenzene at zinc electrodes in a room-temperature ionic liquid: a facile route for the formation of arylzinc compounds.Phys Chem Chem Phys.2014,16(10), 4478-4482.

Jin-Heng Li.; Yun Liang.; De-Ping Wang.; Wen-Jie Liu.; Ye-Xiang Xie.; Du-Lin Yin. Efficient Stille cross-coupling reaction catalyzed by the Pd(OAc)2/Dabco catalytic system.J Org Chem.2005,70(7), 2832-2834.

GHS Hazard and Precautionary Statements

Hazard Statements: H331-H302-H312-H315-H319-H335-H373

Toxic if inhaled. Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P260-P261-P280-P305+P351+P338-P304+P340-P311-P362-P301+P312-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
636964
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2904.90
TSCA
Yes
RTECS
CY9040550

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