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A17750 2,2':6',2''-Terpyridine, 97%

CAS Number
1148-79-4
Synonyms
2,6-Bis(2-pyridyl)pyridine

Stock No. Size Price ($) Quantity Availability
A17750-01 0.25g 46.10
A17750-03 1g 121.00
A17750-06 5g 408.00
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2,2':6',2''-Terpyridine, 97%

MDL
MFCD00006213
EINECS
214-559-5

Chemical Properties

Formula
C15H11N3
Formula Weight
233.28
Melting point
89-92°
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in most organic solvents.

Applications

2,2';6',2"-terpyridine is widely utilized in the field of supramolecular chemistry, which is used to manufacture the racks, ladders and grids, helicates, catenanes and dendrimers. It plays an important role as a ligand in coordination chemistry. Its complexes are employed in the oxidation of alcohols, the carbonylation of aromatic compounds and as oxygen-binding molecules. Functionalized terpyridine ligands were used in semiconductors and solar panels. It forms chealate complexes with europium(III) and terbium(III), which is used in protein labelling.

Notes

Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

Literature References

Schönle, J.; Constable, E. C.; Housecroft, C. E.; Prescimone, A.; Zampese, J. E. Homoleptic and heteroleptic complexes of chromium(III) containing 4'-diphenylamino-2,2':6',2?-terpyridine ligands. Polyhedron 2015, 89 182-188.

Harper, B. W. J.; Aldrich-Wright, J. R. The synthesis, characterisation and cytotoxicity of bisintercalating (2,2':6',2''-terpyridine)platinum(II) complexes. Dalton Trans. 2015, 44 (1), 87-96.

GHS Hazard and Precautionary Statements

Hazard Statements: H300-H310-H315-H319-H335

Fatal if swallowed. Fatal in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P262-P264b-P270-P271-P280-P301+P310-P302+P350-P304+P340-P305+P351+P338-P310-P312-P330-P332+P313-P337+P313-P361-P363-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Gently wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Remove/Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
6.1
Packing Group
I
Harmonized Tariff Code
2933.39
TSCA
Yes

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