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1148-79-4 - 2,2':6',2''-Terpyridine, 97% - 2,6-Bis(2-pyridyl)pyridine - A17750 - Alfa Aesar

A17750 2,2':6',2''-Terpyridine, 97%

CAS Number
1148-79-4
Synonyms
2,6-Bis(2-pyridyl)pyridine

Size Price ($) Quantity Availability
0.25g 44.80
1g 115.00
5g 388.00
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2,2':6',2''-Terpyridine, 97%

MDL
MFCD00006213
EINECS
214-559-5

Chemical Properties

Formula
C15H11N3
Formula Weight
233.28
Melting point
89-92°
Solubility
Soluble in most organic solvents.

Applications

2,2';6',2"-terpyridine is widely utilized in the field of supramolecular chemistry, which is used to manufacture the racks, ladders and grids, helicates, catenanes and dendrimers. It plays an important role as a ligand in coordination chemistry. Its complexes are employed in the oxidation of alcohols, the carbonylation of aromatic compounds and as oxygen-binding molecules. Functionalized terpyridine ligands were used in semiconductors and solar panels. It forms chealate complexes with europium(III) and terbium(III), which is used in protein labelling.

Notes

Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

Literature References

Schönle, J.; Constable, E. C.; Housecroft, C. E.; Prescimone, A.; Zampese, J. E. Homoleptic and heteroleptic complexes of chromium(III) containing 4'-diphenylamino-2,2':6',2?-terpyridine ligands. Polyhedron 2015, 89 182-188.

Harper, B. W. J.; Aldrich-Wright, J. R. The synthesis, characterisation and cytotoxicity of bisintercalating (2,2':6',2''-terpyridine)platinum(II) complexes. Dalton Trans. 2015, 44 (1), 87-96.

GHS Hazard and Precautionary Statements

Hazard Statements: H300-H310-H315-H319-H335

Fatal if swallowed. Fatal in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P262-P301+P310a-P305+P351+P338-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. IF SWALLOWED: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
6.1
Packing Group
I
Harmonized Tariff Code
2933.39
TSCA
Yes

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