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29885-95-8 - N-Methylanilinium trifluoroacetate, 99% - TAMA - Trifluoroacetic acid N-methylanilinium salt - A17781 - Alfa Aesar

A17781 N-Methylanilinium trifluoroacetate, 99%

CAS Number
29885-95-8
Synonyms
TAMA
Trifluoroacetic acid N-methylanilinium salt

N-Methylanilinium trifluoroacetate, 99%

MDL
MFCD00043278
EINECS
249-927-4

Chemical Properties

Formula
C7H10N.CF3CO2
Formula Weight
221.18
Melting point
64-68°
Sensitivity
Hygroscopic

Literature References

In combination with Paraformaldehyde, A11313, ketones undergo direct ɑ-methylenation in high yield: Tetrahedron Lett., 2111 (1978). The reaction proceeds via the Mannich intermediate. For an example (1-tetralone to its 2-methylene derivative), see: Org. Synth. Coll., 7, 332 (1990).

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GHS Hazard and Precautionary Statements

Hazard Statements: H302-H312-H332-H373

Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P260-P280h-P304+P340-P301+P312a-P321-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/clothing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF SWALLOWED: Specific treatment (see label). Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
3638133
Hazard Class
9
Packing Group
III
Harmonized Tariff Code
2921.42
TSCA
No

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