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696-71-9 - Cyclooctanol, 97% - A17825 - Alfa Aesar

A17825 Cyclooctanol, 97%

CAS Number
696-71-9
Synonyms

Size Price ($) Quantity Availability
25g 56.80
100g 180.00
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Cyclooctanol, 97%

MDL
MFCD00001744
EINECS
211-800-6

Chemical Properties

Formula
C8H16O
Formula Weight
128.22
Melting point
14-15°
Boiling Point
97-98°/11mm
Flash Point
86°(186°F)
Density
0.970
Refractive Index
1.4860
Solubility
Miscible with acetone.

Applications

Cyclooctanol is a key starting material used for the preparation of cylooctanone by using a chromic acid reagent.

Notes

Contains 75+% cyclopentane; remainder consists of C{5} and C{6} hydrocarbon.Incompatible with strong oxidizing agents, acid chloride, and acid anhydrides.

Literature References

Oxidation of secondary alcohols to ketones with chromic acid in acetone (Jones' reagent) is exemplified for the preparation of cyclooctanone: Org. Synth. Coll., 5, 310 (1973).

Ren, Y.; Cheng, X.; Yang, K.; Zhu, X.; Li, H.; Wang, Y. Raman study of plastic crystal phase of cyclooctanol under high pressure with different compression rate. J. Mol. Struct. 2015, 1012, 6-10.

Huang, Y. B.; Shen, M.; Wang, X.; Shi, P. C.; Li, H.; Cao, R. Hierarchically micro- and mesoporous metal-organic framework-supported alloy nanocrystals as bifunctional catalysts: Toward cooperative catalysis. J. Catal. 2015, 330, 452-457.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H302-H315-H319

Combustible liquid. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P210u-P280a-P280a-P305+P351+P338-P301+P312a-P501a

Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1848166
Harmonized Tariff Code
2906.19
TSCA
No

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