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A17896 4-Bromostyrene, 98%, stab. with 0.1% 4-tert-butylcatechol

CAS Number
2039-82-9
Synonyms
1-(4-Bromophenyl)ethylene
p-Bromostyrene

Stock No. Size Price ($) Quantity Availability
A17896-06 5g 45.30
A17896-14 25g 154.00
A17896-22 100g 508.00
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4-Bromostyrene, 98%, stab. with 0.1% 4-tert-butylcatechol

MDL
MFCD00000110
EINECS
218-022-6

Chemical Properties

Formula
C8H7Br
Formula Weight
183.05
Melting point
3-6°
Boiling Point
88-89°/16mm
Flash Point
75°(167°F)
Density
1.400
Refractive Index
1.5940
Storage & Sensitivity
Keep Cold.
Solubility
Miscible with ethanol, ether and benzene.

Applications

4-Bromostyrene is widely utilized in the synthesis of nitroolefins by alkene cross-metathesis. It plays an important role in the Heck reaction to the synthesis of poly(1,4-phenylenevinylene). It is employed in the structure activity relationships (SAR) study of the chemical and biochemical properties of the vinyl group of styrene. It is also used to investigate the photochemical growth of Br-terminated self-assembled monolayers. It is also involved in the synthesis of silsesquioxanes.

Notes

Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with acids, bases, oxidizing agents and halogens. Keep away from sources of ignition.

Literature References

Zhang, Y. P.; He, J. H.; Xu, G. Q. Selective Attachment of 4-Bromostyrene on the Si(111)-(7 × 7) Surface. J. Phys. Chem. C 2011, 115 (31), 15496-15501.

Demirel, G. B.; Çakmak, M.; Çaykara, T. Understanding 4-bromostyrene Adsorption on the Si(001)-(1 × 2) surface: A density functional theory study. Surf. Sci. 2011, 605 (11-12), 1056-1061.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H315-H319-H335

Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P302+P352-P305+P351+P338-P312-P332+P313-P337+P313-P362-P370+P378q-P374-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Fight fire with normal precautions from a reasonable distance. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1634204
Harmonized Tariff Code
2903.99
TSCA
No

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