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4-Bromostyrene is widely utilized in the synthesis of nitroolefins by alkene cross-metathesis. It plays an important role in the Heck reaction to the synthesis of poly(1,4-phenylenevinylene). It is employed in the structure activity relationships (SAR) study of the chemical and biochemical properties of the vinyl group of styrene. It is also used to investigate the photochemical growth of Br-terminated self-assembled monolayers. It is also involved in the synthesis of silsesquioxanes.
Zhang, Y. P.; He, J. H.; Xu, G. Q. Selective Attachment of 4-Bromostyrene on the Si(111)-(7 × 7) Surface. J. Phys. Chem. C 2011, 115 (31), 15496-15501.
Demirel, G. B.; Çakmak, M.; Çaykara, T. Understanding 4-bromostyrene Adsorption on the Si(001)-(1 × 2) surface: A density functional theory study. Surf. Sci. 2011, 605 (11-12), 1056-1061.
Hazard Statements: H227-H315-H319-H335
Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P210u-P261-P280a-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.