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A17901 Phenylsilane, 97%

CAS Number
694-53-1
Synonyms

Stock No. Size Price ($) Quantity Availability
A17901-06 5g 78.10
A17901-14 25g 252.00
A17901-22 100g 896.00
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Phenylsilane, 97%

MDL
MFCD00013478
EINECS
211-772-5

Chemical Properties

Formula
C6H8Si
Formula Weight
108.22
Boiling Point
120°
Flash Point
7°(45°F)
Density
0.88
Refractive Index
1.5105
Storage & Sensitivity
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.
Solubility
Contact with water releases a flammable alcohol. Soluble in water (Contact with water releases flammable gases), and most common organic solvents.

Applications

It is used as a pharmaceutical intermediate.

Notes

Moisture Sensitive. Store away from water/moisture. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Protect against electrostatic charges. Keep ignition sources away. Store under inert gas.

Literature References

Richard Apodaca and Wei Xiao. Direct Reductive Amination of Aldehydes and Ketones Using Phenylsilane:? Catalysis by Dibutyltin Dichloride.Org. Lett.,2001,3(11), 1745-1748.

John L. Speier.; Ruth Zimmerman.; James Webster. The Addition of Silicon Hydrides to Olefinic Double Bonds. Part I. The Use of Phenylsilane, Diphenylsilane, Phenylmethylsilane, Amylsilane and Tribromosilane.J. Am. Chem. Soc., 1956,78(10), 2278-2281.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H261-H302+H332-H315-H319-H335

Highly flammable liquid and vapour. In contact with water releases flammable gas. Harmful if swallowed. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P223-P231+P232-P233-P235-P240-P241-P242-P243-P264b-P270-P271-P280-P301+P312-P303+P361+P353-P304+P340-P305+P351+P338-P312-P330-P332+P313-P335+P334-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep away from any possible contact with water, because of violent reaction and possible flash fire. Handle under inert gas. Protect from moisture. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
Yes

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