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A18058 2-Bromo-2-butene, cis + trans, 98%, stab.

CAS Number
13294-71-8
Synonyms

Stock No. Size Price ($) Quantity Availability
A18058-14 25g 97.80
A18058-22 100g 277.00
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2-Bromo-2-butene, cis + trans, 98%, stab.

MDL
MFCD00000141
EINECS
236-316-2

Chemical Properties

Formula
C4H7Br
Formula Weight
135.00
Boiling Point
82-90°
Flash Point
1°(33°F)
Density
1.328
Refractive Index
1.4610
Storage & Sensitivity
Keep Cold.
Solubility
Not miscible or difficult to mix in water (664 mg/L 25 EST).

Applications

Used in the synthesis of substituted catechol derivatives and mono-annelated benzenes.

Notes

Store away from oxidizing agents and heat. Store away from electrostatic charges. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Keep it refrigerated.

Literature References

Gurski A and Liebskind LS. A new process for the regiocontrolled synthesis of substituted catechols and other 1, 2-dioxygenated aromatics: conjugate addition of vinyl-, aryl-, and heteroarylcopper reagents to cyclobutenediones followed by thermal rearrangement.J. Am. Chem. Soc.,1993,115(14), 6101-6108.

Rathore R, et al. Novel synthesis and structures of tris-annelated benzene donors for the electron-density elucidation of the classical Mills-Nixon effect.J. Am. Chem. Soc.,1998,210(24), 6012-6018.

GHS Hazard and Precautionary Statements

Hazard Statements: H225

Highly flammable liquid and vapour.

Precautionary Statements: P210-P233-P240-P241-P242-P243-P280-P303+P361+P353-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1733329
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2903.39
TSCA
Yes

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