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Used in the synthesis of substituted catechol derivatives and mono-annelated benzenes.
Gurski A and Liebskind LS. A new process for the regiocontrolled synthesis of substituted catechols and other 1, 2-dioxygenated aromatics: conjugate addition of vinyl-, aryl-, and heteroarylcopper reagents to cyclobutenediones followed by thermal rearrangement.J. Am. Chem. Soc.,1993,115(14), 6101-6108.
Rathore R, et al. Novel synthesis and structures of tris-annelated benzene donors for the electron-density elucidation of the classical Mills-Nixon effect.J. Am. Chem. Soc.,1998,210(24), 6012-6018.
Hazard Statements: H225
Highly flammable liquid and vapour.
Precautionary Statements: P210-P233-P240-P241-P242-P243-P280-P303+P361+P353-P370+P378q-P501c
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant