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A18235 2,2,2-Trifluoroethyl acrylate, 98%, stab. with 200ppm 4-methoxyphenol

CAS Number
407-47-6
Synonyms
Acrylic acid 2,2,2-trifluoroethyl ester

Stock No. Size Price ($) Quantity Availability
A18235-06 5g 29.30
A18235-14 25g 91.20
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2,2,2-Trifluoroethyl acrylate, 98%, stab. with 200ppm 4-methoxyphenol

MDL
MFCD00000444
EINECS
206-987-6

Chemical Properties

Formula
C5H5F3O2
Formula Weight
154.09
Boiling Point
91-93°
Flash Point
12°(53°F)
Density
1.216
Refractive Index
1.3500
Storage & Sensitivity
Keep Cold.
Solubility
Not miscible or difficult to mix in water.

Applications

It is used for adhesives because of its peeling property and also used for contact lens to give antifouling property. It is also employed as a pharmaceutical intermediate.

Notes

Store away from oxidizing agents, heat, light UV radiation and free radical initiators. Store under inert gas. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Protect from light and electrostatic charges. Keep it refrigerated.

Literature References

Tadashi Narita.; Tokio Hagiwara and Hiroshi Hamana. Anionic polymerization of fluorine-containing vinyl monomers, 2. 2,2,2-trifluoroethyl acrylate and methacrylate.Die Makromolekulare Chemie, Rapid Communications.1985,6(6), 175-178.

Duc V. Le.; Melissa M. Kendrick.; and Edgar A. O'Rear. Admicellar Polymerization and Characterization of Thin Poly(2,2,2-trifluoroethyl acrylate) Film on Aluminum Alloys for In-Crevice Corrosion Control.Langmuir,2004,20(18), 7802-7810.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H315-H319-H335

Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1756611
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2916.12
TSCA
Yes

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    2,2,3,3,4,4,4-Heptafluorobutyl acrylate, 97%, stab. with 100 ppm 4-methoxyphenol

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