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A18320 Ethylene chlorophosphate, 95%

CAS Number
6609-64-9
Synonyms
2-Chloro-1,3,2-dioxaphospholane 2-oxide
2-Chloro-2-oxo-1,3,2-dioxaphospholane

Stock No. Size Price ($) Quantity Availability
A18320-06 5g 66.20
A18320-14 25g 251.00
A18320-22 100g 808.00
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Ethylene chlorophosphate, 95%

MDL
MFCD00043138
EINECS
229-560-6

Chemical Properties

Formula
C2H4ClO3P
Formula Weight
142.48
Melting point
12-14°
Boiling Point
98-99°/2mm
Flash Point
>110°(230°F)
Density
1.56
Refractive Index
1.4500
Storage & Sensitivity
Store at -20°C. Moisture Sensitive. Store under Nitrogen.
Solubility
Miscible with water and chloroform.

Applications

Ethylene chlorophosphate is used in the syntheses of 2-methacryloyoxyethylphophocholine, phosphatidylcholines, 2',3'-O-16-hentriacontanyliden-adenosine-5'-phosphocholine and hexadecylphosphocholine. It is also involved the synthesis of alpha-naphthylphosphorylcholine, which is used to detect phospholipase C activity. It is an important reactant for the synthesis of a zwitterionic silane, UV-polymerizable lipids utilizing Chabrier reaction and block copolymers of poly(aliphatic ester) clickable polyphosphoester.

Notes

Store in cool place. Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with water and reacts violently.

Literature References

Hu, G.; Parelkar, S. S.; & Emrick, T. A facile approach to hydrophilic, reverse zwitterionic, choline phosphate polymers. Polym. Chem. 2015, 6 (4), 525-530.

Rosseto, R.; Hajdu, J. Synthesis of phospholipids on a glyceric acid scaffold: design and preparation of phospholipase A 2 specific substrates. Tetrahedron 2014, 70 (19), 3155-3165.

GHS Hazard and Precautionary Statements

Hazard Statements: H314

Causes severe skin burns and eye damage.

Precautionary Statements: P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
606582
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2934.99
TSCA
No

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