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4001-73-4 - 2-Bromobenzamide, 98% - A18331 - Alfa Aesar

A18331 2-Bromobenzamide, 98%

CAS Number
4001-73-4
Synonyms

Size Price ($) Quantity Availability
5g 45.36
25g 194.67
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2-Bromobenzamide, 98%

MDL
MFCD00007969
EINECS
223-650-9

Chemical Properties

Formula
C7H6BrNO
Formula Weight
200.03
Melting point
160-162°
Solubility
Slightly soluble in water.

Applications

2-Bromobenzamide has been used in microwave assisted one-pot synthesis of substituted 3-(phenylmethylene)isoindolin-1-ones, palladium-catalyzed synthesis of phenanthridinones and in the synthesis of new water-soluble iminophosphorane ligand.

Notes

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literature References

Hellal M and Cuny GD. Microwave assisted copper-free Sonogashira coupling/5-exo-dig cycloisomerization domino reaction: access to 3-(phenylmethylene) isoindolin-1-ones and related heterocycles.Tetrahedron Lett.2011,52(42), 5508-5511.

Chun Lu.; Anton V Dubrovskiy.; Richard C Larock. Palladium-catalyzed annulation of arynes by o-halobenzamides: synthesis of phenanthridinones.J Org Chem.2012,77(19), 8648-8656.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2924.29
TSCA
No

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