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5447-97-2 - 2-Bromo-2-nitropropane, 98% - A18385 - Alfa Aesar

A18385 2-Bromo-2-nitropropane, 98%

CAS Number
5447-97-2
Synonyms

Size Price ($) Quantity Availability
5g 20.62
25g 61.92
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2-Bromo-2-nitropropane, 98%

MDL
MFCD00007389
EINECS
226-668-5

Chemical Properties

Formula
C3H6BrNO2
Formula Weight
168.00
Boiling Point
45-46°/16mm
Flash Point
61°(141°F)
Density
1.584
Refractive Index
1.4640

Literature References

With malonate-type nucleophiles gives ß-nitro esters which, on heating with an alkali metal salt in a dipolar aprotic solvent, undergo elimination to alkenes. The sequence can be carried out in one pot: J. Org. Chem., 48, 3678 (1983); Chem. Lett., 757 (1976):

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GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335-H227

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Combustible liquid.

Precautionary Statements: P210-P261-P280-P305+P351+P338-P304+P340-P362-P312-P405-P403+P233-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1746626
Harmonized Tariff Code
2904.90
TSCA
No

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