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111-24-0 - 1,5-Dibromopentane, 98% - Pentamethylene dibromide - A18465 - Alfa Aesar

A18465 1,5-Dibromopentane, 98%

CAS Number
111-24-0
Synonyms
Pentamethylene dibromide

Size Price ($) Quantity Availability
100g 36.40
500g 120.00
2500g 492.00
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1,5-Dibromopentane, 98%

MDL
MFCD00000268
EINECS
203-849-7

Chemical Properties

Formula
Br(CH2)5Br
Formula Weight
229.95
Melting point
-34°
Boiling Point
224°
Flash Point
79°(174°F)
Density
1.688
Refractive Index
1.5122
Solubility
Miscible with water, slightly miscible with chloroform and benzene.

Applications

1,5-Dibromopentane is used in the preparation of 1,5-di-Grignard reagent and novel spirocyclic pyrrolidones. It acts as a growth supplement for Yarrowia lipolytica 3589, a tropical marine yeast. It is involved in the synthesis of N-alkylated piperidine as well as tetrydrothiopyran (thiane) by reaction with primary amine and sodium sulfide respectively.

Notes

Incompatible with strong oxidizing agents and strong bases.

Literature References

Lifa, T.; Tieu, W.; Hocking, R. K.; Codd, R. Forward and Reverse (Retro) Iron(III) or Gallium(III) Desferrioxamine E and Ring-Expanded Analogues Prepared Using Metal-Templated Synthesis from endo-Hydroxamic Acid Monomers. Inorg. Chem. 2015, 54 (7), 3573-3583.

Perroni, D. V.; Baez-Cotto, C. M.; Sorenson, G. P.; Mahanthappa, M. K. Linker Length-Dependent Control of Gemini Surfactant Aqueous Lyotropic Gyroid Phase Stability. J. Phys. Chem. Lett. 2015, 6 (6), 993-998.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H315-H319-H335

Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P260-P201-P280a-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves and eye/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1209245
Harmonized Tariff Code
2903.39
TSCA
Yes
RTECS
SA0320000

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