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A18465 1,5-Dibromopentane, 98%

CAS Number
111-24-0
Synonyms
Pentamethylene dibromide

Stock No. Size Price ($) Quantity Availability
A18465-22 100g 36.40
A18465-36 500g 120.00
A18465-0E 2500g 512.00
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1,5-Dibromopentane, 98%

MDL
MFCD00000268
EINECS
203-849-7

Chemical Properties

Formula
Br(CH2)5Br
Formula Weight
229.95
Melting point
-34°
Boiling Point
224°
Flash Point
79°(174°F)
Density
1.688
Refractive Index
1.5122
Storage & Sensitivity
Ambient temperatures.
Solubility
Miscible with water, slightly miscible with chloroform and benzene.

Applications

1,5-Dibromopentane is used in the preparation of 1,5-di-Grignard reagent and novel spirocyclic pyrrolidones. It acts as a growth supplement for Yarrowia lipolytica 3589, a tropical marine yeast. It is involved in the synthesis of N-alkylated piperidine as well as tetrydrothiopyran (thiane) by reaction with primary amine and sodium sulfide respectively.

Notes

Incompatible with strong oxidizing agents and strong bases.

Literature References

Lifa, T.; Tieu, W.; Hocking, R. K.; Codd, R. Forward and Reverse (Retro) Iron(III) or Gallium(III) Desferrioxamine E and Ring-Expanded Analogues Prepared Using Metal-Templated Synthesis from endo-Hydroxamic Acid Monomers. Inorg. Chem. 2015, 54 (7), 3573-3583.

Perroni, D. V.; Baez-Cotto, C. M.; Sorenson, G. P.; Mahanthappa, M. K. Linker Length-Dependent Control of Gemini Surfactant Aqueous Lyotropic Gyroid Phase Stability. J. Phys. Chem. Lett. 2015, 6 (6), 993-998.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H302-H315-H319

Combustible liquid. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P210-P264b-P270-P280-P301+P312-P302+P352-P305+P351+P338-P330-P332+P313-P337+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1209245
Harmonized Tariff Code
2903.39
TSCA
Yes
RTECS
SA0320000

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