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A18514 1-Bromo-2,3,4-trifluorobenzene, 99%

CAS Number
176317-02-5
Synonyms
2,3,4-Trifluorobromobenzene

Stock No. Size Price ($) Quantity Availability
A18514-03 1g 20.30
A18514-06 5g 90.60
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1-Bromo-2,3,4-trifluorobenzene, 99%

MDL
MFCD00013248
EINECS
000-000-0

Chemical Properties

Formula
C6H2BrF3
Formula Weight
210.98
Boiling Point
47-49°/60mm
Flash Point
62°(143°F)
Density
1.777
Refractive Index
1.4860
Storage & Sensitivity
Ambient temperatures.
Solubility
Slightly soluble in water.

Applications

1-Bromo-2,3,4-trifluorobenzene is used in synthesis of 5-nitro-6-methylquinoline carboxylic acid.

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Literature References

Christophe Heiss.; Manfred Schlosser. Organometallic Control over the Regiospecificity of Functionalization Reactions: 1,2,3-Trifluorobenzene and Bromo Derivatives thereof as Substrates. European Journal of Organic Chemistry. 2003, 2003 (3), 447-451.

Eric Bosch.; Nathan P. Bowling.; Jeffery Darko. The Power of Nonconventional Phenyl C-H···N Hydrogen Bonds: Supportive Crystal-Packing Force and Dominant Supramolecular Engineering Force. Cryst. Growth Des. 2015, 15 (4), 1634-1641.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H315-H319-H335

Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P235-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
7805451
Harmonized Tariff Code
2903.99
TSCA
No

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