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17639-93-9 - Methyl 2-chloropropionate, 97% - 2-Chloropropionic acid methyl ester - A18541 - Alfa Aesar

A18541 Methyl 2-chloropropionate, 97%

CAS Number
17639-93-9
Synonyms
2-Chloropropionic acid methyl ester

Size Price ($) Quantity Availability
250g 88.83
1000g 244.80
5000g 973.60
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Methyl 2-chloropropionate, 97%

MDL
MFCD00000863
EINECS
241-624-5

Chemical Properties

Formula
C4H7ClO2
Formula Weight
122.55
Melting point
<-10°
Boiling Point
132-133°
Flash Point
38°(100°F)
Density
1.140
Refractive Index
1.4170
Solubility
Insoluble in water

Applications

Methyl 2-chloropropionate is used as initiator during the synthesis of acrylamide homopolymers and acrylamide-N-isopropylacrylamide block copolymers. It is also used to produce 2-thiophen-2-yl-propionic acid methyl ester.

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Literature References

Neugebauer D.; Matyjaszewski K. Copolymerization of N, N-dimethylacrylamide with n-butyl acrylate via atom transfer radical polymerization. Macromolecules. 2003, 36 (8), 2598-2603.

Daniel U. Staerk.; Aroonsiri Shitangkoon.; Eileen Winchester.; Gyula Vigh.; Attila Felinger.; Georges Guiochon. Determination of the gas-liquid partition isotherms of the enantiomers of methyl 2-chloropropionate on trichloroacetyl pentyl β-cyclodextrin using the elution by characteristic points method. Journal of Chromatography A. 1996, 734 (1), 155-162.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H315-H319-H335

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P261-P280-P240-P303+P361+P353-P305+P351+P338-P304+P340-P362-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1421535
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2915.90
TSCA
Yes
RTECS
UE9100000

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