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A18541 Methyl 2-chloropropionate, 97%

CAS Number
17639-93-9
Synonyms
2-Chloropropionic acid methyl ester

Stock No. Size Price ($) Quantity Availability
A18541-30 250g 99.20
A18541-0B 1000g 280.00
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Methyl 2-chloropropionate, 97%

MDL
MFCD00000863
EINECS
241-624-5

Chemical Properties

Formula
C4H7ClO2
Formula Weight
122.55
Melting point
<-10°
Boiling Point
132-133°
Flash Point
38°(100°F)
Density
1.140
Refractive Index
1.4170
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water

Applications

Methyl 2-chloropropionate is used as initiator during the synthesis of acrylamide homopolymers and acrylamide-N-isopropylacrylamide block copolymers. It is also used to produce 2-thiophen-2-yl-propionic acid methyl ester.

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Literature References

Neugebauer D.; Matyjaszewski K. Copolymerization of N, N-dimethylacrylamide with n-butyl acrylate via atom transfer radical polymerization. Macromolecules. 2003, 36 (8), 2598-2603.

Daniel U. Staerk.; Aroonsiri Shitangkoon.; Eileen Winchester.; Gyula Vigh.; Attila Felinger.; Georges Guiochon. Determination of the gas-liquid partition isotherms of the enantiomers of methyl 2-chloropropionate on trichloroacetyl pentyl β-cyclodextrin using the elution by characteristic points method. Journal of Chromatography A. 1996, 734 (1), 155-162.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H315-H319-H335

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1421535
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2915.90
TSCA
Yes
RTECS
UE9100000

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